Citation: HAN Jing, LI Ting, LI Bing. A New Nickel(Ⅱ) Coordination Compound Constructed by Pyridyl-triazole and Oxybis (Benzoic Acid): Synthesis, Crystal Structure and the Effect on the Thermal Decomposition of Ammonium Perchlorate[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 253-259. doi: 10.14102/j.cnki.0254-5861.2011-0461 shu

A New Nickel(Ⅱ) Coordination Compound Constructed by Pyridyl-triazole and Oxybis (Benzoic Acid): Synthesis, Crystal Structure and the Effect on the Thermal Decomposition of Ammonium Perchlorate

1.
Department of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: LI Bing,
Received Date: 23 July 2014
Available Online: 18 December 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21263019) (No. 21263019)

A new energetic complex, Ni(3,4'-Hbpt)₂(Hoba)₂(H₂O)₂ (3,4'-Hbpt=3-(3-pyridyl)-5-(4'-pyridyl)-1-H-1,2,4-triazole and H₂oba=4,4'-oxybis(benzoic acid)), has been synthesized by hydrothermal reaction and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, thermogravimetric analyses and X-ray powder diffraction. Single-crystal X-ray diffraction analysis indicates that the complex belongs to the monoclinic system, space group P2₁/c with a=10.2357(9), b=24.594(2), c=10.4225(9)Å, β=114.0110(10)°, V=2396.7(4)Å³, D_c=1.460 g/cm³, μ=0.482 mm^-1, M_r=1053.63, F(000)=1088, Z=2, the final R=0.0358 and wR=0.0973 with I>2σ(I). Both 3,4'-Hbpt and H2oba ligands adopt monodentate modes linking one Ni(Ⅱ) ion to form a 0D motif. Furthermore, the 0D motifs are linked into a 3D supramolecular architecture with hydrogen bonds. In addition, the catalytic performance for thermal decomposition of the efficacy of ammonium perchlorate (AP) is explored by differential scanning calorimetry (DSC), which indicates that the complex is a good candidate for a promoter of the thermal decomposition of ammonium perchlorate.
- 3-(3-pyridyl)-5-(4'-pyridyl)-1-H-1,2,4-triazole,
- 4,4'-oxybis(benzoic acid),
- crystal structure,
- thermal decomposition,
- ammonium perchlorate
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