Citation: LU Jiu-Fu, LIU Ju, JIANG Min, GE Hong-Guanga. Synthesis, Structure and Luminescent Property of a 2D Cd(Ⅱ) Coordination Polymer Based on Mixed-ligands of 1,3-Bis(imidazol)propane and Pyridine-3,5-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 248-252. doi: 10.14102/j.cnki.0254-5861.2011-0449 shu

Synthesis, Structure and Luminescent Property of a 2D Cd(Ⅱ) Coordination Polymer Based on Mixed-ligands of 1,3-Bis(imidazol)propane and Pyridine-3,5-dicarboxylic Acid

a.
a. Shaanxi University of Technology, Chemical Engineering College, Hanzhong 723001, China;
b.
b. College of Pharmacy, Liaoning University, Shenyang, Liaoning 110036, China

Received Date: 10 July 2014
Available Online: 15 October 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21373132) (No. 21373132)the Science Foundation of Education Department of Shaanxi Provincial Government (No. 12JK0637) (No. 12JK0637)

A new Cd(Ⅱ) coordination polymer, namely, [Cd(1,3-bip)(3,5-pdc)]_n (1,3-bip=1,3-bis(imidazol)propane and 3,5-pdc=pyridine-3,5-dicarboxylic acid) has been synthesized under hydrothermal conditions. Compound 1 was characterized by infrared spectrum, elemental analysis, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P2₁/c with a=1.40178(7), b=1.72502(12), c=1.41635(6) nm, β=92.653(4)°, V=3.4212(3) nm³, Z=4, C₁₆H₁₅CdN₅O₄, M_r=453.73, D_c=1.762 g/cm³, F(000)=1808, μ=1.310 mm^-1, R=0.0899 and wR=0.1945. In compound 1, each 3,5-pdc ligand links three Cd(Ⅱ) ions and each Cd(Ⅱ) attaches to bip ligands to form a complicated 2D double-layer structure. In addition, the thermal stability and luminescent property of 1 have been studied in the solid state at room temperature.
- Cd(Ⅱ) coordination polymer,
- mixed-ligands,
- crystal structure,
- luminescent property
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