Citation: YE Yan-Zhu, LIN Shen, WU Xin-Jian. Synthesis, Structure and Luminescent Property of an Europium(Ⅲ) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1649-1654. doi: 10.14102/j.cnki.0254-5861.2011-0372 shu

Synthesis, Structure and Luminescent Property of an Europium(Ⅲ) Coordination Polymer

a.
a. Department of Science Research and Training, Fujian Institute of Education, Fuzhou 350001, China;
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b. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350108, China

Corresponding author: LIN Shen,
Received Date: 15 May 2014
Available Online: 19 August 2014
Fund Project: This work was financially supported by Foundation of Fujian Educational Committee (JA14348) (JA14348)the National Natural Science Foundation of China (No.21171037) (No.21171037)

A novel europium(Ⅲ) coordination polymer, [Eu₃(pydc)₃(SO₄)(H₂O)₅(ox)_0.5]·3H₂O (1, H₂ox=oxalic acid, H₂pydc=pyridine-2,6-dicarboxylic acid), has been synthesized hydrothermally from the self-assembly of lanthanide ions (Eu³⁺) with the flexible oxalic acid and the rigid pyridine-2,6-dicarboxylic acid ligands, respectively. It crystallizes in the triclinic system, space group P1, with a=11.225(4), b=12.390(5), c=13.752(5)Å, α=89.228(7), β=71.142(6), γ=75.552(6)°, D_c=2.317 g/cm³, μ=5.480 mm^-1, F(000)=1150, Z=2, the final R=0.0351 and wR=0.0949 for 8782 observed reflections with I>2σ(I). Structural analysis reveals that complex 1 exhibits a three-dimensional metal-organic framework via π-π stacking interactions. In addition, complex 1 displays a red fluorescence emission in the solid state at room temperature, which corresponds to the ⁵D₀→⁷F₂ transition of Eu³⁺ ions.
- coordination polymer,
- lanthanide,
- luminescent property
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