Citation: TENG Teng, CHEN Jin, CHEN Xu-Lin, YU Rong-Min, LU Can-Zhong. Synthesis, Crystal Structure and Photoluminescence of a Three-coordinate Ag(Ⅰ) Complex[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1661-1665. doi: 10.14102/j.cnki.0254-5861.2011-0354 shu

Synthesis, Crystal Structure and Photoluminescence of a Three-coordinate Ag(Ⅰ) Complex

TENG Teng ^a,c ,
CHEN Jin ^b ,
CHEN Xu-Lin ^a,c ,
YU Rong-Min ^b ,
LU Can-Zhong ^b

a.
a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 35002, China;
b.
b. College of Life Science, University of Fujian Agriculture and Forestry, Fuzhou 350002, China;
c.
c. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 25 April 2014
Available Online: 30 June 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (51172232) (51172232)

A three-coordinate Ag(Ⅰ) complex, [Ag(Mepzpy)(PAr₃)]BF₄·H₂O (1, Mepzpy=3-methyl-1-(2-pyridyl)pyrazole, PAr₃=tri(o-tolyl)phosphine), was synthesized from the reaction of Ag(CH₃CN)₄BF₄, PAr₃ and Mepzpy in CH₃CN at room temperature. The compound was characterized by UV-vis, NMR and X-ray single-crystal structure analysis. It crystallizes in triclinic space group P1, with a=10.2251(5), b=10.6014(5), c=15.7012(5)Å, α=92.963(3), β=92.641(3), γ=114.647(4)°, V=1540.6(1)Å³, Z=2, M_r=676.24, D_c=1.458 g/cm³, F(000)=688, μ=6.187 mm^-1, GOOF=1.038, the final R=0.0530 and wR=0.1493 for 6371 observed reflections with I>2σ(I). Compound 1 is ionic. It is composed of a BF₄^- anion and a [Ag(Mepzpy)(PAr₃)]⁺ cation. The Ag(Ⅰ) ion adopts a distorted trigonal pyramidal coordination geometry defined by two nitrogen atoms and a phosphorous atom. The complex emits blue luminescence with maximum peaks at 470 nm in solid state at room temperature.
- mononuclear Ag(Ⅰ) complex,
- crystal structure,
- three-coordinate,
- phosphorescence
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