Citation: WEN Bo, WANG Xiao-Dan, YU Ying-Hui, GAO Jin-Sheng, HOU Guang-Feng. Synthesis, Structure and Magnetic Property of One Ni^Ⅱ Based Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1603-1609. doi: 10.14102/j.cnki.0254-5861.2011-0339 shu

Synthesis, Structure and Magnetic Property of One Ni^Ⅱ Based Coordination Polymer

WEN Bo ^a,b ,
WANG Xiao-Dan ^b ,
YU Ying-Hui ^a,b ,
GAO Jin-Sheng ^a,b ,
HOU Guang-Feng ^a,,

a.
a. Engineering Research Centre of Pesticide of Heilongjiang University, Heilongjiang University, Harbin 150080, China;
b.
b. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Corresponding author: HOU Guang-Feng,
Received Date: 15 April 2014
Available Online: 11 September 2014
Fund Project: Supported by the National Natural Science Foundation of China (21371052) (21371052)

One new coordination polymer, [Ni(m-bix)(m-BDC)] (1, m-bix=1,3-bis(imidazol-1-ylmethyl)benzene, m-BDC=1,3-benzenedicarboxylic acids), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1 (C₂₂H₁₈N₄NiO₄) belongs to monoclinic system, space group P2₁/c with a=10.0418(3), b=23.8651(6), c=8.7872(2)Å, β=112.333(3)°, V=1947.88(9)Å³, Z=4, D_c=1.572 g/cm³, M_r=461.11, F(000)=952, R=0.0335 and wR=0.0683 for 2827 observed reflections (I>2σ(I)). Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows antiferromagnetic coupling exchange.
- Ni^Ⅱ complex,
- crystal structure,
- coordination polymer,
- magnetism
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19. [19]
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