Citation: ZHANG Mei-Li, WANG Ji-Jiang, CHEN Xiao-Li. Two Praseodymium Coordination Complexes with 1,3-Phenylenediacetate: Structural Diversity Tuned by Auxiliary Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1623-1628. doi: 10.14102/j.cnki.0254-5861.2011-0326 shu

Two Praseodymium Coordination Complexes with 1,3-Phenylenediacetate: Structural Diversity Tuned by Auxiliary Ligands

1.
Department of Chemistry and Chemical Engineering, Yan'an University, Shaanxi 716000, China

Received Date: 6 April 2014
Available Online: 25 June 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (21373178) (21373178)the Natural Science Foundation of Yan'an University (YDZ2013-09) (1238)

Two new coordination complexes, [Pr(1,3-pda)_0.5(nbca)₂(H₂O)₂] (1) and [Pr₂(1,3-pda)₃(2,2'-bpy)₂(H₂O)₂] (2) (H₂pda=1,3-phenylenediacetic acid, Hnbca=5-nitro [1,1'-biphenyl]-3-carboxylic acid, 2,2'-bpy=2,2'-bipyridine), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. In 1, the nbca ligands bridge the Pr³⁺ ions to form a 1D chain. Moreover, these 1D chains are united together through the 1,3-pda ligands to afford a 2D layer. In contrast, due to a different auxiliary ligand, complex 2 is a 2D layer linked through only bridging deprotonated 1,3-pda. Thermal stabilities and solid fluorescence properties of 1 and 2 were also studied.
- praseodymium(Ⅲ) complexes,
- crystal structures,
- fluorescence properties
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