Citation: LI You-Gui, HAN Lei, MA Gang, ZHU Cheng-Feng. Synthesis, Structure and Property of One Bis(benzimidazolin-2-ylidene) Arene-mercury(Ⅱ) Complex[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1610-1616. doi: 10.14102/j.cnki.0254-5861.2011-0325 shu

Synthesis, Structure and Property of One Bis(benzimidazolin-2-ylidene) Arene-mercury(Ⅱ) Complex

1.
School of Chemical Engineering, Hefei University of Technology, Hefei 230009, China

Corresponding author: LI You-Gui, ZHU Cheng-Feng,
Received Date: 6 April 2014
Available Online: 15 July 2014
Fund Project: This work was supported by the Natural Science Foundation of Anhui Province (11040606M35) (11040606M35)the Fundamental Research Funds for the Central Universities (JZ2014HGBZ0075) (JZ2014HGBZ0075)

Reaction of a N-heterocycliccarbene (NHC) containing an anthracene unit and two N-picolyl moieties with Hg(OAc)₂ yielded a novel mercury(Ⅱ) complex (1). X-ray studies, UV-vis and fluorescence spectroscopy confirmed that a strong interaction exists between the mercury atom and anthracene unit.
- mercury,
- benzimidazolin-2-ylidene,
- carbine,
- fluorescence
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