Citation: GUO Sheng-Nan, HU Yong-Jiao, LIU Hong-Jie, AN Xue, ZOU Ting, KONG Zhi-Guo. A New Porous Cadmium(Ⅱ) Complex Based on 1,10-Phenanthroline Derivative and Dicarboxylate: Syntheses, Structure, Thermal Behavior and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1617-1622. doi: 10.14102/j.cnki.0254-5861.2011-0320 shu

A New Porous Cadmium(Ⅱ) Complex Based on 1,10-Phenanthroline Derivative and Dicarboxylate: Syntheses, Structure, Thermal Behavior and Luminescence

GUO Sheng-Nan ^a,b ,
HU Yong-Jiao ^a,b ,
LIU Hong-Jie ^a,b ,
AN Xue ^a,b ,
ZOU Ting ^a,b ,
KONG Zhi-Guo ^a,b,,

a.
a. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Siping 136000, China;
b.
b. Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: KONG Zhi-Guo,
Received Date: 3 April 2014
Available Online: 22 September 2014
Fund Project:

A new porous Cd(Ⅱ) coordination compound, namely, [Cd(bpdc)(L)₂]·3H₂O (1, L=11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine and bpdc=1,1'-biphenyl-2,2'-dicarboxylate) was synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffraction. It crystallizes in tetragonal, space group P4₁22 with a=9.8486(4), b=9.8486(4), c=45.925(4)Å, V=4454.5(5)Å³, Z=4, C₅₀H₂₉CdF₂N₈O₇, M_r=1004.21, D_c=1.497 g/cm³, F(000)=2028, μ(MoKa)=0.562 mm^-1, R=0.0566 and wR=0.1585. Each Cd(Ⅱ) atom is coordinated by one bpdc anion and two L ligands to give a discrete molecule. Neighboring discrete molecules are stacked by π-π interactions among L ligands, resulting in an interesting 1D supramolecular chain. Moreover, the 1D supramolecular chains are packed with each other to give a porous structure, in which an infinite channel is filled with water molecules. In addition, the thermal behavior and luminescent property of 1 have also been studied.
- coordination compound,
- crystal structure,
- 1,1'-biphenyl-2,2'-dicarboxylate,
- 11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine
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