Citation: Bolin Sun, Jie Chen, Ling Zhou. 乙烯型卤代烃的亲核取代反应[J]. University Chemistry, ;2025, 40(8): 152-157. doi: 10.12461/PKU.DXHX202410032 shu

乙烯型卤代烃的亲核取代反应

College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: Ling Zhou, zhoul@nwu.edu.cn
Received Date: 9 October 2024
Revised Date: 6 January 2025

在基础有机化学教材中，乙烯型卤代烃的亲核取代反应通常被认为是难以发生的。然而，随着近年来研究的深入，化学家们发现多例乙烯型卤代烃的亲核取代反应，并将这类反应命名为烯基亲核取代(Nucleophilic vinylic substitution，S_NV)反应。本文主要介绍已提出的S_NV反应的可能机理，并展示几个典型的S_NV反应实例。将这些前沿进展融入课堂教学，不仅有助于学生了解S_NV反应，而且能够丰富现有的亲核取代反应知识体系。
- Vinylic halides,
- S_NV reaction,
- Nucleophilic substitution,
- Reaction mechanism
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