Citation: Wen Jiang, Jieli Lin, Zhongshu Li. 低配位含磷官能团的研究进展[J]. University Chemistry, ;2025, 40(8): 138-151. doi: 10.12461/PKU.DXHX202409144 shu

低配位含磷官能团的研究进展

School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China

Corresponding author: Zhongshu Li, lizhsh6@mail.sysu.edu.cn
Received Date: 30 September 2024
Revised Date: 26 December 2024

官能团是分子组成的重要构筑基元，决定着分子的物理化学性质。对官能团的结构、性质和功能的研究是合成化学最核心的内容，进而构筑了现代合成化学的理论体系。在“发现和创造新物质”这一化学学科核心工作中，设计和开发新型官能团尤为重要。随着合成技术的进步，逐渐出现了一些含P、B、S、Si等新型官能团的报道。基于对角线规则，含磷官能团可能会表现出类似含碳官能团的性质。同时，磷元素的引入还将进一步调节官能团的位阻和电子性质，从而展现出其独特的物理化学性质和应用潜力。本文综述了近年来低配位含磷官能团，如磷炔、双磷分子、磷宾、磷烯、双磷烯、磷杂苯等的研究进展，并对该领域未来的发展方向进行展望。
- Phosphorus-containing functional groups,
- Diagonal rule,
- Organophosphorus,
- Low-coordinated phosphorus
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