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Citation: Zhenxing Liu, Jiaen Hu, Zishi Cheng, Xinqi Hao. 基础有机化学教学中烯烃的氧化反应[J]. University Chemistry, ;2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107 shu

基础有机化学教学中烯烃的氧化反应

College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Received Date: 26 August 2024
Revised Date: 25 December 2024

本文介绍了几类经典的，但基础教学中没有展开详解的烯烃的氧化反应，包括烯烃的环氧化、四氧化锇氧化、高锰酸钾氧化、臭氧氧化等反应。根据反应机理不同，这些反应被分成三类分别讲述：环氧化反应，双羟化反应和氧化裂解反应；每一部分内容均包含反应通式、机理、典型例子及拓展等。分类讲述有助于学生真正理解并掌握多种氧化反应的异同，典型例子可以加强学生对氧化反应具体应用的理解。除此之外，特在每类反应中加入拓展部分，包括Sharpless环氧化/双羟化和最新发展的双键绿色氧化断裂反应。希望通过对这些反应的总结和拓展切实帮助学生掌握这类重要反应，同时激发学生的科研兴趣，勇于挑战科学前沿。
- Organic chemistry,
- Alkene,
- Oxidation reaction,
- Epoxidation,
- Dihydroxylation,
- Oxidative cleavage
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