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Citation: Xinxin Wu. 基础有机化学教学中自由基重排反应的课程设计及其课程思政元素的融入[J]. University Chemistry, ;2025, 40(6): 316-325. doi: 10.12461/PKU.DXHX202408055 shu

基础有机化学教学中自由基重排反应的课程设计及其课程思政元素的融入

Xinxin Wu

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu Province, China

Received Date: 11 August 2024
Revised Date: 11 November 2024

在有机化学中，重排反应在形成复杂分子结构方面起着关键作用。相比于教科书中传统的离子型重排反应，近年来有关自由基型重排反应的研究日益增多，该领域也逐渐引起了有机化学家们的广泛关注，因此，将自由基重排反应引入有机化学课程中尤为重要。本文重点探讨了自由基型重排反应中的官能团迁移。通过对反应类型、中间体的生成、反应条件和产物类型的对比分析，本文详细阐述了自由基型官能团迁移反应的机制及其在有机合成中的应用。在教学过程中师生共同提升基础有机化学的高阶性。以便鼓励更多基础教学人员能够把自由基重排写入教科书，引入教学课堂，在该部分的授课过程中融合思政元素，引导学生学习国内新一代化学家们的科研创新精神以及家国情怀。
- Rearrangement reactions,
- Radical chemistry,
- Functional group migration,
- Organic chemistry teaching
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