面向本科课堂的有机聚合物导电薄膜制备与改性实验教学创新

引用本文: 贾堡, 柯蕴哲, 孙世悦, 于冬雪, 刘莹, 丁帅帅. 面向本科课堂的有机聚合物导电薄膜制备与改性实验教学创新[J]. 大学化学, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121 shu

Citation: Bao Jia, Yunzhe Ke, Shiyue Sun, Dongxue Yu, Ying Liu, Shuaishuai Ding. Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses[J]. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121 shu

面向本科课堂的有机聚合物导电薄膜制备与改性实验教学创新

贾堡 ^2, ,
柯蕴哲 ^2, ,
孙世悦 ^1, ,
于冬雪 ^2, ,
刘莹 ^2, ,
丁帅帅 ^1,

1.
天津大学分子聚集态科学研究院, 有机集成电路教育部重点实验室, 天津市分子光电科学重点实验室, 天津 300072;
2.
天津大学理学院化学系, 有机集成电路教育部重点实验室, 天津市分子光电科学重点实验室, 天津 300072
基金项目:
国家自然科学基金面上项目(52373250)；国家自然科学基金青年项目(52003190)；天津市科学技术普及项目(22KPXMRC00140)；2023年天津市高等学校研究生教育改革研究计划项目(TJYG017)

摘要: 近年来，作为前沿交叉领域，有机电子学的相关研究方兴未艾。有机电子学旨在使用有机材料制造出更灵活、更环保、更经济的电子器件，用于显示技术、光电子学、能源转换等领域。为深化本科生对有机电子学的理解，本实验教学方案以常见有机聚合物P3HT为主体，利用旋涂仪实现活性层的制备与改性，通过台阶仪、光学显微镜、原子力显微镜表征薄膜表面形貌，最后利用探针台对器件导电性进行测试。实验过程中保护措施规范周全，安全性得到可靠保障，同时实验中包含多项基本操作及实验仪器的使用，有利于提升学生的实践能力和科学素养。本次实验旨在通过对有机聚合物薄膜的制备、改性与测试表征，激发本科生对有机电子学前沿领域的学习兴趣，提升学生的创新意识和综合素质。

关键词:

English

Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses

1.
Key Laboratory of Organic Integrated Circuits, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China;
2.
Key Laboratory of Organic Integrated Circuits, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China
Received Date: 22 April 2024
Revised Date: 17 June 2024
Available Online: 09 July 2024

Abstract: In recent years, research in organic electronics, a burgeoning interdisciplinary field, has seen significant growth. Organic electronics aims to use organic materials to manufacture more flexible, environmentally friendly, and cost-effective electronic devices for applications in display technology, optoelectronics, energy conversion, and other fields. To enhance undergraduate students’ understanding of organic electronics, this experimental teaching plan centers on the commonly used organic polymer P3HT. Using a spin coater, students prepare and modify active layers, then characterize the surface morphology of these films with a step profiler, optical microscope, and atomic force microscope. Conductivity testing of the devices is performed using a probe station. Comprehensive and standardized protective measures ensure safety throughout the experimental process. Additionally, the experiment incorporates fundamental techniques and the use of various instruments, fostering students’ practical skills and scientific literacy. This experiment aims to ignite undergraduates’ interest in the forefront of organic electronics through hands-on preparation, modification, and characterization of organic polymer films, thereby enhancing their innovative thinking and overall competencies.

Key words:

1. [1]
  Yuvaraja, S.; Nawaz, A.; Liu, Q.; Surya, S. G.; Salama, K. N.; Sonar P. Chem. Soc. Rev. 2020, 49 (11), 3423.Yuvaraja, S.; Nawaz, A.; Liu, Q.; Surya, S. G.; Salama, K. N.; Sonar P. Chem. Soc. Rev. 2020, 49 (11), 3423.
2. [2]
  黄维, 密保秀, 高志强. 有机电子学. 第1版. 北京: 科学出版社, 2011: 13-27.
3. [3]
  Wang, J. C.; Cai, G. L.; Jia, B. Y.; Lu, H.; Lu, X. H.; Zhan, X. W.; Chen, X. G. J. Mater. Chem. A 2021, 9 (10), 6520.Wang, J. C.; Cai, G. L.; Jia, B. Y.; Lu, H.; Lu, X. H.; Zhan, X. W.; Chen, X. G. J. Mater. Chem. A 2021, 9 (10), 6520.
4. [4]
  Huynh, W. U.; Dittmer. J. J.; Alivisatos, A. P. Science 2002, 295 (5564), 2425.Huynh, W. U.; Dittmer. J. J.; Alivisatos, A. P. Science 2002, 295 (5564), 2425.
5. [5]
  Chong, L.-W.; Chou, Y.-N.; Lee, Y.-L.; Wen, T.-C.; Guo, T.-F. Org. Electron. 2009, 10 (6), 1141.Chong, L.-W.; Chou, Y.-N.; Lee, Y.-L.; Wen, T.-C.; Guo, T.-F. Org. Electron. 2009, 10 (6), 1141.
6. [6]
  Hao, R. F.; Yue Y. F.; Li, L. L.; Ji, J. L.; Zhang, Q.; Ding, L. F.; Sang, S. B.; Li, Q. J. Biotechnol. 2022, 359, 75.Hao, R. F.; Yue Y. F.; Li, L. L.; Ji, J. L.; Zhang, Q.; Ding, L. F.; Sang, S. B.; Li, Q. J. Biotechnol. 2022, 359, 75.
7. [7]
  胡文平. 有机场效应晶体管. 第1版. 北京: 科学出版社, 2015: 25-26.
8. [8]
  Forrest, S. R. Organic Electronics: Foundations to Applications; Oxford University Press: Oxford, UK, 2020; pp. 804-806,626-627.Forrest, S. R. Organic Electronics: Foundations to Applications; Oxford University Press: Oxford, UK, 2020; pp. 804-806,626-627.
9. [9]
  Ren, Y.; Yang, X. Y.; Zhou, L.; Mao, J.-Y.; Han, S.-T.; Zhou, Y. Adv. Funct. Mater. 2019, 29 (40), 1902105.Ren, Y.; Yang, X. Y.; Zhou, L.; Mao, J.-Y.; Han, S.-T.; Zhou, Y. Adv. Funct. Mater. 2019, 29 (40), 1902105.
10. [10]
  查朝云. 电子制作, 2016, No. 15, 14.
11. [11]
  Luo, D. X.; Chen, Q.; Liu, B. Q.; Qiu, Y. Polymers 2019, 11 (2), 384.Luo, D. X.; Chen, Q.; Liu, B. Q.; Qiu, Y. Polymers 2019, 11 (2), 384.
12. [12]
  Tang, C. W. Appl. Phys. Lett., 1986, 48 (2), 183.Tang, C. W. Appl. Phys. Lett., 1986, 48 (2), 183.
13. [13]
  Yin, Y. ACE., 2023, 7 (1), 291.Yin, Y. ACE., 2023, 7 (1), 291.

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沈阳化工大学材料科学与工程学院沈阳 110142

面向本科课堂的有机聚合物导电薄膜制备与改性实验教学创新

English

Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

面向本科课堂的有机聚合物导电薄膜制备与改性实验教学创新

English

Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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