Citation: CHEN Chonglai, ZHANG Wenxia, QIU Jianping, JIA Aiping, LUO Mengfei. Catalytic Decomposition of Ozone by Manganese Oxide Supported on Cordierite Honeycomb Ceramics[J]. Chinese Journal of Applied Chemistry, ;2020, 37(11): 1293-1300. doi: 10.11944/j.issn.1000-0518.2020.11.200143 shu

Catalytic Decomposition of Ozone by Manganese Oxide Supported on Cordierite Honeycomb Ceramics

a.
College of Pharmaceutics and Materials Engineering, Jinhua Polytechnic, Jinhua, Zhejiang 321017, China
b.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LUO Mengfei, mengfeiluo@zjnu.cn
Received Date: 14 May 2020
Revised Date: 19 June 2020
Accepted Date: 8 July 2020

Figures(8)

A series of different manganese oxides was mixed with aluminum gel and coated to cordierite honeycomb ceramics to produce monolithic catalysts for improving the application ability of catalysts. The performances of these monolithic catalysts in the decomposition of ozone at ambient temperature and pressure were investigated. The structures of these catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), BET specific surface area method and H₂-programmed temperature reduction (H₂-TPR) techniques. The results show that the activities of different manganese oxide supported monolithic catalysts are arranged in the following order:OMS-2 (Manganese oxide octahedral molecular sieve) > MnO₂ > Mn₂O₃ > Mn₃O₄ > MnO. Compared with other manganese oxides, OMS-2 supported cordierite honeycomb ceramics monolithic catalyst has the highest activity to decompose ozone, probably due to the fact that OMS-2 has a larger specific surface area and better reducibility, which are favorable for the oxygen vacancy formation on the surface and participation in the decomposition of ozone. The results of this paper provide a theoretical basis for improving the performance of cordierite honeycomb ceramic supported monolithic catalyst for ozone decomposition.
- ozone,
- manganese oxide octahedral molecular sieve,
- cordierite honeycomb ceramics,
- monolithic catalysts
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沈阳化工大学材料科学与工程学院沈阳 110142