Citation: XIAO Haimei, CAI Lei, ZHANG Zhaohui, CHEN Shan, ZHOU Shu, FU Jinli. Preparation of Ion-Imprinted Polymers Based on Magnetic Graphene Oxide/MIL-101 (Cr) and Selective Adsorption of Cu(Ⅱ) and Pb(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;2020, 37(9): 1076-1086. doi: 10.11944/j.issn.1000-0518.2020.09.200028 shu

Preparation of Ion-Imprinted Polymers Based on Magnetic Graphene Oxide/MIL-101 (Cr) and Selective Adsorption of Cu(Ⅱ) and Pb(Ⅱ)

XIAO Haimei ^a ,
CAI Lei ^a ,
ZHANG Zhaohui ^a,b,c,, ,
CHEN Shan ^a ,
ZHOU Shu ^a ,
FU Jinli ^a

a.
College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hu'nan 416000, China
b.
Key Laboratory of Mineral Cleaner Production and Exploit of Green Functional Materials in Hu'nan Province, Jishou University, Jishou, Hu'nan 416000, China
c.
State Key Laboratory of Chemo Biosensing and Chemometrics, Hu'nan University, Changsha 410082, China

Corresponding author: ZHANG Zhaohui, zhaohuizhang77@163.com
Received Date: 20 January 2020
Revised Date: 2 April 2020
Accepted Date: 11 May 2020

Fund Project: Hunan Province Graduate Student Scientific Research Innovation Project CX2018B705National Natural Science Foundation of China 21565014Hunan Province Manganese Zinc and Vanadium Industry Technology Collaborative Innovation Center Research and Innovation Project 2018mzvg006Supported by the National Natural Science Foundation of China(No.21767011, No.21565014), the Hunan Province Graduate Student Scientific Research Innovation Project(No.CX2018B705), and the Hunan Province Manganese Zinc and Vanadium Industry Technology Collaborative Innovation Center Research and Innovation Project(No.2018mzvg006)National Natural Science Foundation of China 21767011

Figures(9)

A type of magnetic ion-imprinted polymer based on magnetic graphene oxide/MIL-101(Cr) was synthesized with surface imprinting technology using magnetic graphene oxide/MIL-101(Cr) composite as the supporting material, Cu(Ⅱ), Pb(Ⅱ) as the templates, and dopamine as the functional monomer. Fourier-transform infrared spectroscopy, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the morphology, particle size, and magnetic properties of the magnetic ion-imprinted polymer. The adsorption kinetics, isothermal adsorption performance and adsorption selectivity of the magnetic ion-imprinted polymer toward Cu(Ⅱ) and Pb(Ⅱ) were investigated in details. The results show that the magnetic ion-imprinted polymer has a superior adsorption performance toward Cu(Ⅱ) and Pb(Ⅱ) with the maximum adsorption capacity of 144.92 and 322.58 mg/g, respectively. The magnetic solid-phase extraction conditions were optimized in details. The magnetic ion-imprinted polymer was successfully used for the separation and detection of trace amounts of Cu(Ⅱ) and Pb(Ⅱ) in water samples. The recoveries of Cu(Ⅱ) and Pb(Ⅱ) are 81.99%~89.91% and 81.24%~95.15%, respectively.
- magnetic ion-imprinted polymer,
- surface imprinting,
- metal ion,
- magnetic graphene oxide,
- MIL-101(Cr)
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