Citation: CHEN Songhua, CHEN Xin, LIU Yongqi, HE Meiyun, FU Shanshan, PENG Li, YANG Jien. Self-assembly and Luminescence Properties of Intramolecular Charge Transfer Compound of Carbazole Derivatives[J]. Chinese Journal of Applied Chemistry, ;2020, 37(9): 1022-1029. doi: 10.11944/j.issn.1000-0518.2020.09.200015 shu

Self-assembly and Luminescence Properties of Intramolecular Charge Transfer Compound of Carbazole Derivatives

CHEN Songhua ^a ,
CHEN Xin ^b ,
LIU Yongqi ^a ,
HE Meiyun ^a ,
FU Shanshan ^a ,
PENG Li ^a ,
YANG Jien ^c,,

a.
College of Chemistry and Material, Longyan University, Longyan, Fujian 364000, China
b.
National Science Library, Chinese Academy of Sciences, Beijing 100190, China
c.
School of Materials Science and Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Corresponding author: YANG Jien, yjen@htu.edu.cn
Received Date: 13 January 2020
Revised Date: 21 April 2020
Accepted Date: 21 May 2020

Fund Project: Supported by the Research Funds of Longyan University(No.LB2018016), the Science and Technology Program of Longyan(No.2018LYF8007), and the Science and Technology Program of Henan(No.192102210173)the Science and Technology Program of Longyan No.2018LYF8007Research Funds of Longyan University No.LB2018016the Science and Technology Program of Henan No.192102210173

Figures(6)

In order to study the optical properties of intramolecular charge transfer compounds of small organic molecular systems with donor-acceptor structure, two kinds of π-conjugated intramolecular charge transfer(ICT)derivatives ((E)-4-((4-(4-(9H-carbazol-9-yl)styryl)phenyl)ethynyl)-7-bromobenzo[c][1, 2, 5]thiadiazole (CzPB-Br) and 4, 7-bis((4-((E)-4-(9H-carbazol-9-yl)styryl)phenyl)ethynyl)benzo[c][1, 2, 5]thiadiazole (CzPBPCz)) were synthesized, where the donor part consists of carbazole unit, while benzothiadiazole works as the acceptor. The influence of different conjugated groups on the structure and photophysical properties were studided by ultraviolet-visible (UV-Vis) spectra, fluorescence spectra and theoretical calculations. CzPB-Br and CzPBPCz have characteristic UV-Vis absorption peaks at 404 and 442 nm in CH₂Cl₂, respectively, with the maximum fluorescence wavelengths at 557 and 588 nm, respectively. The well-defined one-dimensional microrods and polygonal micron plates in large quantities and with high morphological purity are successfully fabricated adopting a phase transfer methodology and precipitation of hot saturated solution, exhibiting green and yellow emission respectively (emission maximum centered at 515 and 568 nm). The length of one-dimensional microrod is more than 100 μm with the width of 1~2 μm. Meanwhile, these assembles show a typical characteristics of waveguiding behavior, endowing potential applications in the field of optical devices.
- carbazole,
- benzothiadiazole,
- aggregated structure,
- self-assemble,
- luminescence properties
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