Citation: DONG Zhiyun, LIU Yang, WANG Yingjin, ZHAO Sanhu, XI Fugui. Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-[J]. Chinese Journal of Applied Chemistry, ;2020, 37(7): 839-846. doi: 10.11944/j.issn.1000-0518.2020.07.200004 shu

Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-

Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: XI Fugui, xifuguig@163.com
Received Date: 2 January 2020
Revised Date: 24 February 2020
Accepted Date: 27 March 2020

Fund Project: Supported by the National Natural Science Foundation of China(No.21701137), and the Shanxi "1331 Project" Key Subjects Construction(2019)the National Natural Science Foundation of China 21701137the Shanxi "1331 Project" Key Subjects Construction 2019

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Two novel naphthalimide-benzimidazolium based receptors 1 and 2 were synthesized. The anion (F^-, Cl^-, Br^-, I^-, CH₃COO^-, HSO₄^-, H₂PO₄^-, ClO₄^-, NO₃^-) binding properties of two receptors were evaluated in CH₃CN by fluorescence spectroscopy. Two receptors display fluorescent quenching effect with H₂PO₄^- and the quench percentages for receptors 1 and 2 are 98%and 24%, respectively. The results indicate that receptor 1 is more closely matched to H₂PO₄^- in configuration, and receptor 1 behaves as a "turn-off" fluorescence sensor for H₂PO₄^-. Job-plot shows that receptor 1 and H₂PO₄^- form a 1:1 complex, and the binding constant is (1.25±0.11)×10⁵ L/mol, the detection limit is 6.90×10^-6 mol/L.
- benzimidazolium,
- naphthalimide,
- H₂PO₄^-,
- fluorescent sensor
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沈阳化工大学材料科学与工程学院沈阳 110142

Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H2PO4-

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通讯作者: 陈斌, bchen63@163.com

Naphthalimide-Benzimidazolium Based Fluorescent Chemosensor for Highly Selective Recogniton of H₂PO₄^-