Citation: ZHANG Yanhui, WANG Lin, MUSLIM Arzugul, LAN Haidie. Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline[J]. Chinese Journal of Applied Chemistry, ;2020, 37(7): 764-771. doi: 10.11944/j.issn.1000-0518.2020.07.190360 shu

Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline

Electrochemical Engineering Center, School of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi 830054, China

Corresponding author: MUSLIM Arzugul, arzu_hma@sina.com
Received Date: 30 December 2019
Revised Date: 10 March 2020
Accepted Date: 24 April 2020

Fund Project: Supported by the National Natural Science Foundation of China(No.51763023), and the Scientific Research Plan for Universities of Xinjiang(No.XJEDU2017S028)the Scientific Research Plan for Universities of Xinjiang XJEDU2017S028the National Natural Science Foundation of China 51763023

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Use of amphiphilic block copolymers as templates is one of the effective methods to construct conducting polymer nanostructures and adjust their morphologies and sizes. The change of the length of core-forming block has a significant effect on their micellization behavior, and then changes the morphology and size of conducting polymers limited by their micelle morphology. The change of morphology and size will inevitably lead to the change of electrochemical properties of conducting polymers. In this paper, the morphology and size of polyaniline (PANI) were controlled and its electrochemical performance was optimized by block copolymer template induction. Polystyrene-b-poly(acrylic acid) (PS_x-b-PAA₇₀, x=38, 64, 101) was successfully synthesized by reversible addition-fragmentation chain transfer radical polymerization (RAFT) and its self-assembled micelles were used as templates to prepare PANI. When the length of core forming block is shorter, the PANI shows rod-like particles with diameters 100~200 nm. When x=101, PANI presents spatial network structure and has the highest discharge specific capacitance. When the current density is 1 A/g, its discharge specific capacity can reach 386.71 F/g.
- polystyrene-b-poly(acrylic acid),
- block copolymer template,
- polyaniline,
- capacitance
1. [1]
  Gibson T J, Peter S, Mcdaid W J. Single-Domain Antibody-Functionalized pH-Responsive Amphiphilic Block Copolymer Nanoparticles for Epidermal Growth Factor Receptor Targeted Cancer Therapy[J]. ACS Macro Lett, 2018,7(8):1010-1015. doi: 10.1021/acsmacrolett.8b00461
2. [2]
  Lü J H, Yu Y, Gao J F. Thermo-Responsive Amphiphilic Block Copolymers Stablilized Gold Nanoparticles:Synthesis and High Catalytic Properties[J]. Langmuir, 2018,34(28):8205-8214. doi: 10.1021/acs.langmuir.8b00414
3. [3]
  Park S H, Ahn Y, Jang M. Effects of Methacrylate Based Amphiphilic Block Copolymer Additives on Ultra Filtration PVDF Membrane Formation[J]. Sep Purif Technol, 2018,202:34-44. doi: 10.1016/j.seppur.2018.03.018
4. [4]
  Li Z J, Sun J J, Huang Y X. A Nanomicellar Prodrug Carrier Based on Ibuprofen-Conjugated Polymer for Co-delivery of Doxorubicin[J]. Front Pharmacol, 2018,9:781-792. doi: 10.3389/fphar.2018.00781
5. [5]
  Yoo S I, Sohn B H, Wang C Z. Localized Synthesis of Polypyrrole in the Nanopattern of Monolayer Films of Diblock Copolymer Micelles[J]. Langmuir, 2004,20:10734-10736. doi: 10.1021/la048171v
6. [6]
  Yin Z G, Zheng Q D. Controlled Synthesis and Energy Application of One-Dimensional Conducting Polymer Nanostructures:An Overview[J]. J Phys Chem B, 2010,114:1314-1324. doi: 10.1021/jp910636s
7. [7]
  DONG Jianhua. The Frontier and Development of Polymer Science[M]. Beijing:Science Press, 2006:516(in Chinese).
8. [8]
  Zhao Z X, Muslim A, Abdunazar A. Preparation of Polybenzidine Submicrorods with Controllable Morphology Using Poly(ethylene oxide)-b-Polystyrene as a Template and Its Electrochemical Properties[J]. J Macromol Sci A, 2017,54(10):727-734. doi: 10.1080/10601325.2017.1332462
9. [9]
  Bucholz T, Sun Y M, Loo Y L. Near-Monodispersed Polyaniline Particles Through Template Synthesis and Simultaneous Doping with Diblock Copolymers of PMA and PAAMPSA[J]. J Mater Chem, 2008,18:5835-5842. doi: 10.1039/b810849h
10. [10]
  Benaglia M, Rizzardo E, Alberti A. Searching for More Effective Agents and Conditions for the RAFT Polymerization of MMA:Influence of Dithioester Substituents, Solvent, and Temperature[J]. Macromolecules, 2005,38(8):3129-3140. doi: 10.1021/ma0480650
11. [11]
  ZHU Hui, LIU Shiyong, PAN Quanming. Synthesis of Amphiphilic Block Copolymer Poly(styrene-b-acrylic acid) by Atom Transfer Radical Polymerization and Its Micellization[J]. Chem J Chinese Univ, 2002,23(1):138-142. doi: 10.3321/j.issn:0251-0790.2002.01.026
12. [12]
  SUN Chunhui, CAO Xia, FU Peng. Synthesis of Block Copolymer Poly(ε-Caprolactone)₄-b-Poly(Acrylic Acid)₄[J]. Polym Mater Sci Eng, 2012,28(1):41-44.
13. [13]
  HUA Man, YANG Wei, XUE Qiao. Study on Synthesis of Amphiphilic PS-b-PMAA and Their Micellization[J]. Acta Chim Sin, 2005,63(7):631-636. doi: 10.3321/j.issn:0567-7351.2005.07.014
14. [14]
  Huang J, Virji S, Weiller B H. Polyaniline Nanofibers:Facile Synthesis and Chemical Sensors[J]. J Am Chem Soc, 2003,125(2):314-315. doi: 10.1021/ja028371y
15. [15]
  Ghosh T, Ghosh R, Basak U. Candle Soot Derived Carbon Nanodot/Polyaniline Hybrid Materials Through Controlled Grafting of Polyaniline Chains for Supercapacitors[J]. J Mater Chem A, 2018,6:6476-6492. doi: 10.1039/C7TA11050B
16. [16]
  GAO Lei, LIAO Yi, ZHANG Xiaohua. Preparation and Enhanced Electrocapacitive Properties of Polyaniline Nanothorns on the Surface of Nitrogen Doped Hollow Carbon Spheres[J]. Chem J Chinese Univ, 2013,34(12):2845-2849. doi: 10.7503/cjcu20130366
17. [17]
  KAN Kan, FU Dong, WANG Jue. Preparation and Capacitive Performance of Interconnected Composite Nanowire Based on Polyaniline Coated Carbon Nanofiber[J]. Fine Chem, 2019,36(10):2060-2067.
18. [18]
  ZHAO Qiang, LV Mangeng. Synthesis of Three-Dimensional Ordered Polyaniline-Graphene Nanocomposite and Its Application for Supercapacitor Electrode[J]. Fine Chem, 2016,33(6):635-642.
19. [19]
  Chen W, Xia C, Rakhi R B. A General Approach toward Enhancement of Pseudocapacitive Performance of Conducting Polymers by Redox-Active Electrolytes[J]. J Power Sources, 2014,267(4):521-526.
20. [20]
  Liu Y, Ma Y, Guang S. Facile Fabrication of Three Dimensional Highly Ordered Structural Polyaniline-Graphene Bulk Hybrid Materials for High Performance Supercapacitor Electrodes[J]. J Mater Chem A, 2014,2:813-823. doi: 10.1039/C3TA13513F
21. [21]
  Wang Y, Shi Z, Huang Y. Supercapacitor Devices Based on Graphene Materials[J]. J Phys Chem C, 2009,113:13103-13107. doi: 10.1021/jp902214f
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