Citation: ZHANG Zhuanfang, ZHENG Jianhua, XIN Jianjiao, ZHAO Nan, CHEN Jie, XU Rui. Syntheses and Catalytic Properties of Keggin-Type Polyoxometalate-Based Crystal Materials[J]. Chinese Journal of Applied Chemistry, ;2020, 37(4): 481-488. doi: 10.11944/j.issn.1000-0518.2020.04.190268 shu

Syntheses and Catalytic Properties of Keggin-Type Polyoxometalate-Based Crystal Materials

Center of Teaching Experiment Management Equiment, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: ZHANG Zhuanfang, zzfhao2014@163.com
Received Date: 12 October 2019
Revised Date: 19 December 2019
Accepted Date: 17 February 2020

Fund Project: Supported by the Education Department Basic Business of Heilongjiang(No.135309452)the Education Department Basic Business of Heilongjiang 135309452

Figures(8)

By introducing polyoxotungstates [PW₁₂O₄₀]^3- into the Co-bbp(bbp:3, 5-bis(pyrid-4-yl)pyridine) system, a new polyoxometalate-based inorganic-organic hybrid, [Co(Hbbp)₂][PW₁₂O₄₀] (1), was synthesized under the hydrothermal condition. The structure was determined by single-crystal X-ray diffraction analysis. Structural analyses show that metal Co coordinates with bbp to form the metal-organic monomer which stacks through π…π bond between ligands to from a two-dimensional layered framework structure. [PW₁₂O₄₀]^3- is embedded into the gaps as the template, forming a multi-acid-based supramolecular compound. The properties of compound 1 was investigated, and the results indicate that the degradation ratio of rhodamine B (RhB) reaches 94% after 120 min (under visible light). In addition, compound 1 is a multifunctional catalyst and has good electrocatalytic activities towards the reduction of NO₂^- and oxidation of ascorbic acid.
- Keggin polyoxometalate,
- supramolecular compound,
- hydrothermal syntheses,
- catalytic property
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