Citation: HOU Chengmin, ZHANG Wei, XIA Weimin, ZHANG Zhifa, KOU Yanping. Wear Resistance of Ultraviolet Curing Water-Based Ink and Ink Film[J]. Chinese Journal of Applied Chemistry, ;2020, 37(4): 464-470. doi: 10.11944/j.issn.1000-0518.2020.04.190257 shu

Wear Resistance of Ultraviolet Curing Water-Based Ink and Ink Film

School of Printing, Packaging Engineering and Digital Media Technology, Xi'an University of Technology, Xi'an 710048, China

Corresponding author: HOU Chengmin, 1042067175@qq.com
Received Date: 29 September 2019
Revised Date: 18 December 2019
Accepted Date: 14 February 2020

Fund Project: Supported by the National Natural Science Foundation of China(No.52803167), and the Shaanxi Provincial Natural Science Fund(No.2016JQ2029)the National Natural Science Foundation of China 52803167the Shaanxi Provincial Natural Science Fund 2016JQ2029

Figures(6)

Traditional ultraviolet (UV) inks have the advantages of low viscosity, fast curing speed, and wide application range. However, there are disadvantages such as use of organic solvents and low degree of crosslinking. In this paper, styrene and acrylic acid are copolymerized by free radical polymerization to form aqueous prepolymer. Secondly, a tetraacrylate functional reactive diluent is prepared from glycidyl methacrylate (GMA) and ethylenediamine. Finally, a UV-curable aqueous ink is prepared using an aqueous prepolymer, a reactive diluent, a photoinitiator, and a small amount of solvent. The effects of the type and mass fraction of the photoinitiator, the relative molecular mass and mass fraction of the prepolymer, the structure and mass fraction of the reactive diluent on the photocuring speed and wear resistance of the UV ink are investigated. When the prepolymer has a relative molecular mass of 1.98×10⁵ and a mass fraction of 30%, a photoinitiator mass fraction of 4%, a reactive diluent functional group number of 4, and a mass fraction of 40%, the photocuring rate of the UV aqueous ink is 1 s. After 50 times the wear quality loss is 9%. The UV aqueous ink prepared by the method can be used for flexographic printing, gravure printing, and digital printing.
- ultrabiolet water-based ink,
- prepolymer,
- photocuring,
- reactive diluent
1. [1]
  ZOU Lianhong. Research on Non-VOCs Offset Sheetfed Environmentally Friendly Ink[D]. Tianjin: Tianjin University, 2018(in Chinese).
2. [2]
  WANG Zhengxiang, LI Yunhua, DENG Qi. Preparation of UV Curing Waterborne Polyurethane Based Ink[J]. Pack J, 2016,8(1):21-24.
3. [3]
  Zhou X, Li Y, Fang C. Recent Advances in Synthesis of Waterborne Polyurethane and Their Application in Water-based Ink:A review[J]. J Mater Sci, 2015,31(7):708-722.
4. [4]
  LOU Lili, JIANG Pingping, XIA Jialiang. Current Status of Water-based Ink Research[J]. New Chem Mater, 2013,41(1):9-11. doi: 10.3969/j.issn.1006-3536.2013.01.003
5. [5]
  YAN Jifang, WANG Qi, HUANG Beiqing. Synthesis and Application of Room Temperature Self-crosslinking Pure Acrylic Emulsion for Water-based Ink[J]. Fine Chem, 2019,36(4):764-770.
6. [6]
  Zhang H, Massingill J L, Woo J T K. Low VOC, Low Viscosity UV Cationic Radiation-Cured Ink-Jet Ink System[J]. J Coat Technol Res, 2000,72(6):45-52. doi: 10.1007/BF02757875
7. [7]
  Zhai D, Zhang T, Guo J. Water-based Ultraviolet Curable Conductive Inkjet Ink Containing Silver Nano-colloids for Flexible Electronics[J]. Colloid Surf A-Physicochem Eng Asp, 2013,424:1-9. doi: 10.1016/j.colsurfa.2013.01.055
8. [8]
  HUANG Beiqing, WANG Lianzhi, JIN Yangzhi. Study on the Effect of Composite Photoinitiator on the Curing Speed of UV Ink[J]. Thermoset Resin, 2001,16(6):35-37. doi: 10.3969/j.issn.1002-7432.2001.06.011
9. [9]
  Granat P, Pudas M, Hormi O. Synthesis of Acrylated Ethylcellulose for UV-Curing Ink[J]. Carbohydr Polym, 2004,57(2):225-228. doi: 10.1016/j.carbpol.2004.04.014
10. [10]
  Gallart-Ayala H, Núñez O, Moyano E. Analysis of UV Ink Photoinitiators in Packaged Food by Fast Liquid Chromatography at Sub-ambient Temperature Coupled to Tandem Mass Spectrometry[J]. J Chromatogr A, 2011,1218(3):459-466. doi: 10.1016/j.chroma.2010.11.054
11. [11]
  Bahria H, Erbil Y. UV Technology for Use in Textile Dyeing and Printing:Photocured Applications[J]. Dyes Pigm, 2016,134:442-447. doi: 10.1016/j.dyepig.2016.07.042
12. [12]
  Jafarifard S, Bastani S, Soleimani-Gorgani A. The Chemo-Rheological Behavior of an Acrylic Based UV-Curable Inkjet Ink:Effect of Surface Chemistry for Hyperbranched Polymers[J]. Prog Org Coat, 2016,90:399-406. doi: 10.1016/j.porgcoat.2015.08.007
13. [13]
  Liang B, Li R, Zhang C. Synthesis and Characterization of a Novel Tri-functional Bio-based Methacrylate Prepolymer from Castor Oil and Its Application in UV-curable Coatings[J]. Ind Crop Prod, 2019,135:170-178. doi: 10.1016/j.indcrop.2019.04.039
14. [14]
  Liu X, Xie D, Wu J. Synthesis of Water-Soluble Epoxy Resin Modified Acrylic Resin for Water-Based Ink[J]. Pack Eng, 2008,29(7):31-33.
15. [15]
  Cesur B, Karahan O, Agopcan S. Difunctional Monomeric and Polymeric Photoinitiators:Synthesis and Photoinitiating Behaviors[J]. Prog Org Coat, 2015,86:71-78.
16. [16]
  Yagci Y, Jockusch S, Turro N J. Photoinitiated Polymerization:Advances, Challenges, and Opportunities[J]. Macromolecules, 2010,43(15):6245-6260. doi: 10.1021/ma1007545
17. [17]
  Dietliker K, Jung T, Benkhoff J, et al. New Developments in Photoinitiators[C]//Macromolecular Symposia. Weinheim: WILEY-VCH Verlag, 2004, 217(1): 77-98.
18. [18]
  Angiolini L, Caretti D, Salatelli E. Synthesis and Photoinitiation Activity of Radical Polymeric Photoinitiators Bearing Side-Chain Camphorquinone Moieties[J]. Macromol Chem Phys, 2000,201(18):2646-2653. doi: 10.1002/1521-3935(20001201)201:18<2646::AID-MACP2646>3.0.CO;2-D
19. [19]
  Park S K, Kwark Y J, Nam S. A Variation in Wrinkle Structures of UV-Cured Films with Chemical Structures of Prepolymers[J]. Mater Lett, 2017,199:105-109.
20. [20]
  MA Yanjun, YE Yinping, CHEN Lei. Optimization Design of UV Curing Polyurethane Acrylate Binder[J]. Polym Mater Sci Eng, 2018,34(5):111-115.
1. [1]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
2. [2]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
3. [3]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
8. [8]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
9. [9]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
10. [10]
  Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
11. [11]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154
12. [12]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
13. [13]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
14. [14]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
17. [17]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
20. [20]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(785)
HTML views(197)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142