Citation: ZHANG Tianyong, Ren Zhongjing, LI Bin, JIANG Shuang, SHI Jixing, SHI Zhiqiang, LÜ Dongjun. An Efficient Method for Improved Preparation of C.I. Pigment Red 177 Intermediate[J]. Chinese Journal of Applied Chemistry, ;2020, 37(4): 433-439. doi: 10.11944/j.issn.1000-0518.2020.04.190251 shu

An Efficient Method for Improved Preparation of C.I. Pigment Red 177 Intermediate

ZHANG Tianyong ^a,b ,
Ren Zhongjing ^a ,
LI Bin ^a,, ,
JIANG Shuang ^a,, ,
SHI Jixing ^a ,
SHI Zhiqiang ^c ,
LÜ Dongjun ^d,e

a.
Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China
b.
Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China
c.
Department of Chemical Engineering, Renai College, Tianjin University, Tianjin 301636, China
d.
Yuhong Pigment Co. Ltd, Dezhou, Shandong 253000, China
e.
Shangdong Engineering Technology Research Center for the Whole Process Control of Organic Pigment's Cleaner Production, Dezhou, Shandong 253000, China

Corresponding author: LI Bin, libin@tju.edu.cn JIANG Shuang, shuangjiang@tju.edu.cn
Received Date: 20 September 2019
Revised Date: 12 December 2019
Accepted Date: 18 February 2020

Fund Project: the Natural Science Foundation of Tianjin 16JCYBJC20800the National Natural Science Foundation of China 21908161Supported by the National Natural Science Foundation of China(No.21908161), the Tianjin Science and Technology Innovation Platform Program(No.14TXGCCX00017), the Natural Science Foundation of Tianjin(No.16JCYBJC20800)the Tianjin Science and Technology Innovation Platform Program 14TXGCCX00017

Figures(6)

The effect of batch addition of the catalyst (copper powder) on the reaction rate during the synthesis of 4, 4'-diamino-1, 1'-dianthraquinone-3, 3'-disulfonic acid (DAS) was investigated systematically. The results indicate that 55 ℃ is the preferred reaction temperature. Copper powder and sodium bromate with a mass ratio of of 2:5 are first added, and the second portion of catalyst with a mass ratio of 1:5 copper powder to sodium bromate is then added during the reaction. The reaction time could be saved for 2~3 h compared to adding copper powder at one time (the mass ratio of copper powder to sodium bromate is 3:5). The copper salt mixed in DAS could be removed efficiently by addition of citric acid during the preparation process, which can improve the purity of DAS. When the mass ratio of copper powder to citric acid is 6:1, the content of copper salt in DAS is less than 0.001%. In addition, the influence of the residual amount of the filtrate after distillation on the yield of DAS is also explored and the yield of DAS is above 95% when the remaining amount of filtrate is 20 mL. The results of this study also indicate that to further improve the yield of the reaction, more efficient catalyst is needed.
- C.I. Pigment red 177 intermediate,
- catalyst,
- copper powder,
- citric acid
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沈阳化工大学材料科学与工程学院沈阳 110142