Citation: WANG Chunli, SUN Lianshan, ZHONG Ming, WANG Limin, CHENG Yong. Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries[J]. Chinese Journal of Applied Chemistry, ;2020, 37(4): 387-404. doi: 10.11944/j.issn.1000-0518.2020.04.190243 shu

Research Progress of Transition Metal and Compounds for Lithium-Sulfur Batteries

WANG Chunli ^a,b ,
SUN Lianshan ^a,c ,
ZHONG Ming ^d ,
WANG Limin ^a,b ,
CHENG Yong ^a,,

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
c.
Institute for Energy Research, Key Laboratory of Zhenjiang, Jiangsu University, Zhenjiang, Jiangsu 212013, China
d.
Jiangxi JXTC Haoyun High-tech Co., Ltd, Nanchang 330096, China

Corresponding author: CHENG Yong, cyong@ciac.ac.cn
Received Date: 11 September 2019
Revised Date: 2 November 2019
Accepted Date: 17 December 2019

Fund Project: the National Key Research and Development Program of China 2017YFE9128100Supported by the National Key Research and Development Program of China(No.2017YFE9128100)

Figures(10)

Lithium-sulfur batteries are considered to be the next-generation secondary batteries with development potentials due to high theoretical specific capacity and low cost. However, there are several limitations of the sulfur cathodes due to the insulating nature of sulfur and Li₂S, the "shuttle effect" caused by the intermediate lithium polysulfides(Li₂S_x, 4≤x≤8) dissolved and migrated in the electrolyte and serious side effects, resulting in low utilization of the active materials, poor cycling stability and rate performances. In this paper, the research progress of transition metal nano materials in lithium-sulfur batteries is reviewed. Especially, the synthetic methods of materials and the reaction mechanism for inhibiting the dissolution of lithium polysulfide and promoting the conversion are introduced and the development of cathode carrier materials for lithium-sulfur batteries is forecasted.
- transition metal compounds,
- nanomaterials,
- lithium sulfur battery,
- electrochemical performances,
- chemical adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142