Citation: SUN Jinyu, WANG Guilin, SHI Yufang, LIU Chengqi, ZHAO Minggen. Synthesis, Theoretical Investigation and Ultrafast Third-Order Nonlinear Optical Response of 2-(Pyren-1-yl)-1, 8-naphthyridine[J]. Chinese Journal of Applied Chemistry, ;2019, 36(10): 1172-1178. doi: 10.11944/j.issn.1000-0518.2019.10.190035 shu

Synthesis, Theoretical Investigation and Ultrafast Third-Order Nonlinear Optical Response of 2-(Pyren-1-yl)-1, 8-naphthyridine

Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: SHI Yufang, yfshi868@163.com
Received Date: 13 February 2019
Revised Date: 15 April 2019
Accepted Date: 15 May 2019

Fund Project: Supported by the Shanxi "1331 Project" Key Subjects Construction(No.2017-122)the Shanxi "1331 Project" Key Subjects Construction 2017-122

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A new donor-acceptor(D-A) pyrene-containing naphthalene derivative 2-(pyrene-1-yl)-1, 8-naphthyl was synthesized and characterized by nuclear magnetic resonance spectrometry(¹H NMR, ¹³C NMR), Fourier transform infrared spectrometry(FTIR) and liquid chromatography-mass spectrometry(LC-MS). The linear optical properties and third-order nonlinear optical absorption of 2-(pyrene-1-yl)-1, 8-naphthyridine(PN) were studied by means of the electron spectroscopy and Z-scan technique, respectively. The thermal stability of PN was determined by thermogravimetry and differential scanning calorimetry. The experimental results show that the nonlinear absorption coefficient of PN at 532 nm and 180 fs is β=9.0×10^-14 m/W, exhibiting ultrafast third-order nonlinear optical response. The molecular orbital energy, polarizability and hyperpolarizability were calculated by density functional theory, and the results show that electron transfer can take place within the molecule. There is no absorbance at more than 450 nm in ultraviolet spectrum of PN. So it is a candidate material for the next in nonlinear optical absorption, laser protection, absorption optical switch or bistable devices.
- pyrene-containing naphthalene derivative,
- Z-scan technique,
- theoretical calculation,
- ultrafast third-order nonlinear optical properties
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