Citation: QIAO Zongwen, CHEN Tao. Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 917-923. doi: 10.11944/j.issn.1000-0518.2019.08.190013 shu

Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells

QIAO Zongwen ^a,, ,
CHEN Tao ^b

a.
Department of Chemical Engineering, Shaanxi Institute of Technology, Xi'an 710300, China
b.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: QIAO Zongwen, qiaozongwen@126.com
Received Date: 14 January 2019
Revised Date: 22 February 2019
Accepted Date: 17 April 2019

Fund Project: Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Project of Shaanxi Institute of Technology Gfy18-04Natural Science Special Project of Shaanxi Education Department 18JK0069Supported by Natural Science Special Project of Shaanxi Education Department(No.18JK0069), Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Project of Shaanxi Institute of Technology(No.Gfy18-04)

Figures(6)

Chloromethylated polysulfones(CPS) was used as the precursors, and side chain type sulfonted polysulfone(PS-BDS) was obtained using disodium 1, 2-dihydroxybenzene-3, 5-disufonate as nucleophilic reagents. The corresponding proton exchange membranes(PEMs) were produced using solution casting method. The relationship between the temperature and properties of PEMs was studied. Since they have characteristic micro-phase separation structures by locating hydrophilic sulfonic acid group far away from hydrophobic main chain of PS, PEMs have excellent dimensional stability at high water sorption ratio. With the increase of temperature, the proton conductivity, the swelling ratio and the water sorption ratio increase. PS-BDS PEMs have comprehensive size stability and methanol permeability. The swelling ratio of PS-BDS-4 PEM is only 22.1% at 25℃ and 55.0% at 85℃. The methanol permeability is 9.94×10^-7 cm²/s at 25℃, lower than those of commercial Nafion115(16.8×10^-7 cm²/s) and Nafion117(23.8×10^-7 cm²/s) PEMs.
- polysulfone,
- exchange membranesphase separation,
- dimensional stability,
1. [1]
  Kima K, Junga B K, Koa T. Polysulfones Containing Sulfonated Polytriazole Side Chains for Proton Exchange Membranes[J]. J Membr Sci, 2018,554(15):232-243.
2. [2]
  Liu D, Xu M Z, Fang M L. Branched Comb-shaped Poly(arylene ether sulfone)s Containing Flexible Alkyl Imidazolium Side Chains as Anion Exchange Membranes[J]. J Mater Chem, 2018,6:10879-10890. doi: 10.1039/C8TA02115E
3. [3]
  Yan X M, Zhang C M, Dong Z W. Amphiprotic Side-Chain Functionalization Constructing Highly Proton/Vanadium-Selective Transport Channels for High-Performance Membranes in Vanadium Redox Flow Batteries[J]. Appl Mater Interfaces, 2018,10(38):32247-32255. doi: 10.1021/acsami.8b11993
4. [4]
  Li X, Zhao Y, Li W W. Molecular Dynamics Simulation of Radiation Grafted FEP Films as Proton Exchange Membranes:Effects of the Side Chain Length[J]. Int J Hydrogen Energy, 2017,42(50):29977-29987. doi: 10.1016/j.ijhydene.2017.09.043
5. [5]
  Han M M, Zhang G, Li M Y. Sulfonated Poly(etheretherketone) Polybenzimidazole Oligomer/Epoxy Resin Composite Membranes in Situ Polymerization for Direct Methanol Fuel Cell Usages[J]. J Power Sources, 2011,196:9916-9923. doi: 10.1016/j.jpowsour.2011.08.049
6. [6]
  QIAO Zongwen, YAN Xiaoqian. Properties of Naphthalenesulfonic Acid Type Polysulfone Proton Exchange Membrane[J]. Chem Res Appl, 2018,30(12):1993-1998. doi: 10.3969/j.issn.1004-1656.2018.12.011
7. [7]
  Kumar P, Dutta K, Das S. Membrane Prepared by Incorporation of Crosslinked Sulfonated Polystyrene in the Blend of PVdF-co-HFP/Nafion[J]. Appl Energy, 2014,123:66-74. doi: 10.1016/j.apenergy.2014.02.060
8. [8]
  RONG Qian, GU Shuang, HE Gaohong. Preparation and Performance of Sulfonated Polyether Ether/Ketone/Poly4-Vinylepyridine Acid-Base Composite Proton Exchange Membrane[J]. Polym Mater Sci Eng, 2009,8:126-129.
9. [9]
  GONG Feixiang, QI Yonghong, XUE Qunxiang. Synthesis and Properties of Fluorinated Poly(arylene ether sulfone)s with Sulfonated Pentiptycene Pendants as Proton Exchange Membranes[J]. Chem J Chinese Univ, 2014,35:433-439. doi: 10.7503/cjcu20130605
10. [10]
  Jin C H, Zhu X L, Zhang S. Highly Conductive Flexible Alkylsulfonated Side Chains Poly(phthalazinone ether ketone)s for Proton Exchange Membranes[J]. Polymer, 2018,148(18):269-277.
11. [11]
  Zhang X L, Shi Q, Chen P. Block Poly(arylene ether sulfone) Copolymers Tethering Aromatic Side-Chain Quaternary Ammonium as Anion Exchange Membranes[J]. Polym Chem, 2018,9:699-711. doi: 10.1039/C7PY01558E
12. [12]
  QIAO Zongwen, CHEN Tao. Effect of Side Chain Structure on Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes[J]. Chem Bull, 2019,82(5):457-462.
13. [13]
  Liu D, Tao D, Ni J P. Synthesis and Properties of Highly Branched Sulfonated Poly(arylene ether)s with Flexible Alkylsulfonated Side Chains as Proton Exchange Membranes[J]. J Mater Chem C, 2016,4:1326-1335.
14. [14]
  Pang J H, Shen K Z, Feng S N. Polymer Electrolyte Membranes Based on Poly(arylene ether)s with Flexible Disulfophenyl Pendant[J]. J Power Sources, 2014,263:59-65. doi: 10.1016/j.jpowsour.2014.03.100
15. [15]
  TAO Dan, XIANG Xiongzhi, WANG Lei. Synthsis and Characterization of Poly(arylene ether)s Proton Exchange Membranes with Sulfonic Groups Attached on Pendent Naphthyl Rings[J]. Acta Polym Sin, 2014,3:326-332.
16. [16]
  Ekström H, Lafitte B, Ihonen J. Evaluation of a Sulfophenylated Polysulfone Membrane in a Fuel Cell at 60 to 110℃[J]. Solid State Ionics, 2007,178:959-966. doi: 10.1016/j.ssi.2007.04.002
17. [17]
  Zhang Y, Wan Y, Zhao C J. Novel Side-Chain-Type Sulfonated Poly(arylene ether ketone) with Pendant Sulfoalkyl Groups for Direct Methanol Fuel Cells[J]. Polymer, 2009,50:4471-4478. doi: 10.1016/j.polymer.2009.07.036
1. [1]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
2. [2]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
5. [5]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
6. [6]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
7. [7]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
8. [8]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
9. [9]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
10. [10]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
11. [11]
  Jie WU , Zhihong LUO , Xiaoli CHEN , Fangfang XIONG , Li CHEN , Biao ZHANG , Bin SHI , Quansheng OUYANG , Jiaojing SHAO . Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400
12. [12]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
13. [13]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
14. [14]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
15. [15]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
16. [16]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
17. [17]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
18. [18]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
19. [19]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
20. [20]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(364)
HTML views(59)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142