Citation: YU Huifa, CHEN Chonglai, WANG Yuejuan, LUO Mengfei. Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts[J]. Chinese Journal of Applied Chemistry, ;2019, 36(6): 698-703. doi: 10.11944/j.issn.1000-0518.2019.06.180328 shu

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts

a.
Key Laboratory of Advanced Catalytic Materials, Ministry of Education, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
b.
Jinhua Vocational and Technical College, Jinhua, Zhejiang 321004, China

Corresponding author: LUO Mengfei, mengfeiluo@zjnu.cn
Received Date: 12 October 2018
Revised Date: 12 December 2018
Accepted Date: 23 January 2019

Figures(5)

A series of NiO/Mn₃O₄ monolithic catalysts with different NiO contents was prepared by ball-milling of Ni(NO₃)₂·6H₂O, Mn₃O₄ and pseudo boehmite precusors via subsequent impregnation with cordierite, followed by calcination. These catalysts were tested for ozone decomposition. It was found that the 30NiO/Mn₃O₄(mass fraction of NiO in total mass is 30%) catalyst has the highest activity at a space velocity of 20000 h^-1, and leads to 98% conversion of ozone, while the catalyst remains stable. When the space velocity is increased to 40000 h^-1, the 50NiO/Mn₃O₄(mass fraction of NiO in total mass is 50%) catalyst gives the highest activity, with a ozone conversion at about 90%. But the catalyst suffers deactivation. Characterizations by X-ray diffraction(XRD), TPR, XPS and BET reveal that the presence of Mn₃O₄ in the NiO increases the specific surface area of the catalyst, and electronic interaction between Mn₃O₄ and NiO. Meanwhile, the co-presence of Mn₃O₄ and NiO in the catalyst results in facile reduction of these oxides. This synergy is believed to be responsible for the enhanced catalytic performance.
- Mn₃O₄,
- NiO,
- catalyst,
- Ozone decomposition,
- active site
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts