Citation: TANG Jing, LIN Xiaoyi, ZHOU Wenyan, HUANG Qiuying. Synthesis, Crystal Structure and Recognition Properties of One-Dimensional Luminescent Cd Coordination Polymer[J]. Chinese Journal of Applied Chemistry, ;2019, 36(4): 459-464. doi: 10.11944/j.issn.1000-0518.2019.04.180264 shu

Synthesis, Crystal Structure and Recognition Properties of One-Dimensional Luminescent Cd Coordination Polymer

a.
Department of Chemical Engineering, He'nan Polytechnic Institute, Nanyang, He'nan 473009, China
b.
Department of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China
c.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China

Corresponding author: HUANG Qiuying, huangqy72@163.com
Received Date: 14 August 2018
Revised Date: 21 September 2018
Accepted Date: 26 October 2018

Fund Project: the Henan Province Foundation and Advanced Technology Research Project 162300410206the Foundation of Henan Educational Committee 16B150002Supported by the National Natural Science Foundation of China(No.J1210060), the Henan Province Foundation and Advanced Technology Research Project(No.162300410206), the Foundation of Henan Educational Committee(No.16B150002)the National Natural Science Foundation of China J1210060

Figures(5)

By reaction of an aryl substituted imidazole dicarboxylate ligand 2-(4-cyanophenyl)-1H-imidazole-4, 5-dicarboxylic acid(p-CNPhH₃IDC) with cadmium nitrate, in the presence of N-containing chelate ligand, 2, 2'-bipyridine(2, 2'-bipy), a one-dimensional chain-like coordination polymer, [Cd(p-CNPhHIDC)(2, 2'-bipy)]_n(1) with mixed ligands was prepared hydrothermally. The structure and properties of the coordination polymer were studied by elemental analysis, Fourier transform infrared spectrometer and single crystal X-ray diffraction. The results show that the coordination polymer has good thermal stability under 231.6℃. After being soaked in acetonitrile, methanol, acetaldehyde and other solvents, the fluorescence intensity of coordination polymer 1 was weakened(aldehyde, CH₂Cl₂) or enhanced(DMF, nitrobenzene and acetone) to a certain extent. A 60 nm blue shift in its fluorescence emission, in pyridine indicated a good identification effect on pyridine by this polymer.
- Cd-polymer,
- imidazole dicarboxylate,
- crystal structure,
- recognition properties
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沈阳化工大学材料科学与工程学院沈阳 110142