Citation: SHI Yanlong, FENG Xiaojuan, KANG Kai, HOU Yang. Fabrication of Superhydrophobic-Superoleophobic Surfaces by Facile Solution-Immersion and Surface Coating[J]. Chinese Journal of Applied Chemistry, ;2019, 36(3): 358-366. doi: 10.11944/j.issn.1000-0518.2019.03.180243 shu

Fabrication of Superhydrophobic-Superoleophobic Surfaces by Facile Solution-Immersion and Surface Coating

College of Chemistry and Chemical Engineering, Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, Hexi University, Zhangye, Gansu 734000, China

Corresponding author: SHI Yanlong, yanlongshi726@126.com
Received Date: 13 July 2018
Revised Date: 5 September 2018
Accepted Date: 23 October 2018

Fund Project: the Scientific Research Foundation of the Higher Education Institutions of Gansu Province 2016B-091the General Program of the Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities XZ1603Supported by the National Natural Science Foundation of China(No.41761061), the Scientific Research Foundation of the Higher Education Institutions of Gansu Province(No.2016B-091), and the General Program of the Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities(No.XZ1603)the National Natural Science Foundation of China 41761061

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Superhydrophobic-superoleophobic materials have received considerable attention due to their wide potential applications in the fields of anti-fouling, water-proof and oil-proof. In this paper, superhydrophobic-superoleophobic zinc spheres are first prepared by immersing the zinc spheres into the solution of perfluorooctanoic acid, and then the superhydrophobic-superoleophobic surfaces are obtained by pasting the obtained superhydrophobic-superoleophobic zinc spheres on substrates of glass, wood, plastic, stainless steel, paper and stone. The contact angles of water and oil droplets on these surfaces all exceed 150°. Zinc spheres react with perfluorooctanoic acid to form zinc perfluorooctanoate, and the coordinate effects of micro/nanometer rough structures and chemical composition with low surface energy of the long fluoroalkyl lead to the formation of superhydrophobicity and superoleophobicity. The research may offer a new idea for the design and fabrication of superamphiphobic materials, as well as their application in self-cleaning, waterproof, oil-proof and anti-contamination.
- superhyrophobicity,
- superoleophobicity,
- superamphiphobicity,
- zinc perfluorooctanoate,
- solution immersion
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