Citation: SUN Jinyu, WANG Yingjin, SHI Yufang, REN Guangming, ZHAO Minggen. Synthesis of Two Ferrocene-Based Chalcone Derivatives and Their Ultrafast Third-Order Nonlinear Optical Response[J]. Chinese Journal of Applied Chemistry, ;2019, 36(3): 282-290. doi: 10.11944/j.issn.1000-0518.2019.03.180216 shu

Synthesis of Two Ferrocene-Based Chalcone Derivatives and Their Ultrafast Third-Order Nonlinear Optical Response

Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: SHI Yufang, yfshi868@163.com
Received Date: 20 June 2018
Revised Date: 22 August 2018
Accepted Date: 28 September 2018

Fund Project: the Fund for Shanxi "1331 Project" Key Subjects Construction 2017-42Supported by the Fund for Shanxi "1331 Project" Key Subjects Construction(No.2017-42)

Figures(7)

Two ferrocene-based isomeric chalcone derivatives 1-ferrocenly-3-(thiophen-2-yl) prop-2-en-1-one(a) and 1-(ferrocenly)-3-(thiophen-3-yl) prop-2-en-1-one(b) were synthesized. Their third-order nonlinear optical properties were measured by Z-scan technique with ultrafast laser operating at 532 nm laser in 180 fs pulse, respectively. The relevant parameters were given as follows:the nonlinear absorption coefficient β=-2.1×10^-12 m/W, the nonlinear refractive index n₂=1.9×10^-19 m²/W and the third-order nonlinear hyperpolarizability γ=5.37×10^-32 esu for compound a; β=-1.2×10^-13 m/W, n₂=2.0×10^-19 m²/W and γ=4.48×10^-32 esu for compound b. The results indicate that the excitation of femtosecond laser enables intramolecular charge transfer to occur quickly. Thus two compounds can exhibit ultrafast third-order nonlinear optical response. The orbital energies, polarizabilities and possession ratios of different groups in frontier molecular orbitals of compounds a and b were calculated by B3LYP/6-311+G(d, p) level. The percentage of ferrocene group in the frontier molecular orbitals of compounds a and b is 97% and 98%, respectively, which indicates that ferrocene group plays a leading role in the nonlinear optical properties of two compounds.
- chalcone derivatives,
- Z-scan technique,
- theoretical simulation,
- ultrafast third-order nonlinear optical response
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