Citation: XIA Dongdong, HOU Yaqi, PAN Qianxia, HE Zihui, YANG Jianzhe, WANG Haibo. Adsorption of p-Nitrobenzene Derivatives by Polyacrylate Organic Membranes Based on 1, 4-Dimethoxy Pillar[5]arenes[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 24-33. doi: 10.11944/j.issn.1000-0518.2019.01.180054 shu

Adsorption of p-Nitrobenzene Derivatives by Polyacrylate Organic Membranes Based on 1, 4-Dimethoxy Pillar[5]arenes

College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: WANG Haibo, wanghaibo@njtech.edu.cn
Received Date: 27 February 2018
Revised Date: 28 April 2018
Accepted Date: 7 June 2018

Figures(17)

Pillararenes are columnar macrocyclic molecules that are different from crown ethers, calixarenes, and cucurbiturils, and have unique electron-rich cavities and modifiable mouth cavities. They can contain a variety of organic pollutants, and have broad application prospects for the adsorption and removal of organic pollutants. In this paper, the complexation of p-nitrobenzene derivatives with 1, 4-dimethoxy pillar[5]arenes(MeP5A) was studied by nuclear magnetic resonance and ultraviolet titration, and the inclusion constant was determined. On this basis, MeP5A was physically mixed into polyacrylate(PA) emulsion to prepare the MeP5A/polyacrylate(MeP5A/PA) blending emulsion. Then, the blending emulsion was made into the MeP5A/PA nanofiber membrane by the electrospinning technology. The structure and morphology of the MeP5A/PA nanofiber membrane were characterized by infrared spectroscopy and scanning electron microscopy. The MeP5A/PA nanofiber membrane was used for adsorption of four kinds of p-nitrobenzene derivatives. The results reveal that p-nitrophenylacetonitrile holds the strongest complexation intensity with MeP5A[K_a=(6.0±0.3)×10² L/mol]. The introduction of MeP5A into the PA nanofiber membrane increases the adsorption capacity but does not change the fibrous morphology. The optimum adsorption equilibrium time of MeP5A/PA nanofiber membranes is 2 h, and the higher the content of MeP5A in MeP5A/PA nanofiber membranes, the larger the adsorption capacity. When the concentration of MeP5A in the adsorbed solution reaches 4 mmol/L(the corresponding MeP5A mole in the membrane is 1.4×10^-2 mmol), the adsorption equilibrium is reached. Then the content of MeP5A continues to increase, and the adsorption capacity does not change much.
- dimethoxy pillar[5]arenes,
- inclusion constants,
- nanofiber membrane,
- adsorption
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