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Citation: ZHANG Baohua, SHI Lanxiang. Regioselective Synthesis of Dibenzo[d, f] [1, 3]dioxepines[J]. Chinese Journal of Applied Chemistry, ;2018, 35(11): 1331-1334. doi: 10.11944/j.issn.1000-0518.2018.11.170429 shu

Regioselective Synthesis of Dibenzo[d, f] [1, 3]dioxepines

ZHANG Baohua ,
SHI Lanxiang ^,

College of Chemical Engineering, Shijiazhuang University, Shijiazhuang 050035, China

Corresponding author: SHI Lanxiang, kedashilanxiang@163.com
Received Date: 27 November 2017
Revised Date: 15 January 2018
Accepted Date: 5 February 2018

Figures(2)

In order to overcome the shortcomings of facile production of dihydroxy diphenyl ethylene by-product in traditional method, dibenzo [d, f][1, 3] dioxepines was synthesized highly regioselectively from a broad range of terminal alkynes with Lewis acidic guanidinium ionic liquid catalyst in 39%~84% yields. The Lewis acidic guanidinium ionic liquid can be reused five times without significantly decrease in catalytic activity.
- guanidinium ionic liquid,
- dibenzo [d, f][1, 3] dioxepine,
- dihydroxybiphenyl,
- terminal alkyneterminal alkyne
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