Citation: LIU Yongjun, ZHONG Ming, SONG Cheng, SHENG Shouri, HOU Haoqing, SONG Caisheng. Synthesis and Characterization of Poly (aryl ether ether ketone ketone) Containing Phenyl Phosphine Oxide[J]. Chinese Journal of Applied Chemistry, ;2018, 35(11): 1289-1294. doi: 10.11944/j.issn.1000-0518.2018.11.170409 shu

Synthesis and Characterization of Poly (aryl ether ether ketone ketone) Containing Phenyl Phosphine Oxide

School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330027, China

Corresponding author: SONG Cheng, sonyia416@gmail.com
Received Date: 14 November 2017
Revised Date: 12 January 2018
Accepted Date: 5 February 2018

Fund Project: the Department of Education, Research Program of Jiangxi Province GJJ12214the Science and Technology Landing Program Project of Jiangxi′s Universities KJLD14022Supported by the National Natural Science Foundation of China(No.51663011), the Science and Technology Landing Program Project of Jiangxi′s Universities(No.KJLD14022), the Department of Education, Research Program of Jiangxi Province(No.GJJ12214)the National Natural Science Foundation of China 51663011

Figures(8)

A kind of poly (aryl ether ether ketone ketone) containing phenyl phosphine oxide structure (P-PEEKK) was synthesized by polycondensation of bis (4-phenoxy phenyl) phenyl phosphine oxide (BPOPPO) synthesized from phenol, 1, 4-dibromobenzene and phenylphosphonic dichloride as raw materials and terephthaloyl chloride (TPC) with aluminum chloride (AlCl₃) as the catalyst. The structure and properties of P-PEEKK resin were characterized by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA) and wide-angle X-ray diffraction (WAXD), etc. The results show that P-PEEKK resin is amorphous with a high glass transition temperature (T_g) of 190.5℃, a thermal decomposition temperature (T_5%) of 515℃, limiting oxygen index (LOI) of 42 and tensile strength of 62 MPa, and is soluble in chloroform, 1, 2-dichloroethane, N, N-dimethylacetamide and other organic solvents for coating film.
- bis(phenoxy phenyl) phenyl phosphine oxide,
- terephthaloyl chloride,
- poly(aryl ether ether ketone ketone)
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