Citation: ZHU Yuezhou, ZHANG Yuejiao, LI Jianfeng, REN Bin, TIAN Zhongqun. Surface-Enhanced Raman Spectroscopy: Applications and Perspectives[J]. Chinese Journal of Applied Chemistry, ;2018, 35(9): 984-992. doi: 10.11944/j.issn.1000-0518.2018.09.180172 shu

Surface-Enhanced Raman Spectroscopy: Applications and Perspectives

College of Chemistry and Chemical Engineering, Xiamen University, Fujian, Xiamen 361005, China

Corresponding author: LI Jianfeng, Li@xmu.edu.cn TIAN Zhongqun, zqtian@xmu.edu.cn
Received Date: 14 May 2018
Revised Date: 15 May 2018
Accepted Date: 22 May 2018

Fund Project: the National Natural Science Foundation of China 21533006the National Natural Science Foundation of China 21775127the National Natural Science Foundation of China 21522508Supported bu the National Natural Science Foundation of China(No.21533006, No.21522508, No.21775127)

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Surface-enhanced Raman spectroscopy (SERS) is a fingerprint spectroscopic technique with ultra-high sensitivity. It has been widely used in surface science, material science, biomedicine, drug analysis, food safety inspection, and pollutant detection, as a promising technique for trace analysis. In this paper, we comprehensively reviewed the development and applications of SERS and related techniques, including tip-enhanced Raman spectroscopy (TERS), shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS), and discussed its research frontiers and development directions in the future.
1. [1]
  Raman C V, Krishnan K S. A New Type of Secondary Radiation[J]. Nature, 1928,121:501-502.
2. [2]
  Fleischmann M, Hendra P J, McQuillan A J. Raman Spectra of Pyridine Adsorbed at a Silver Electrode[J]. Chem Phys Lett, 1974,26(2):163-166.
3. [3]
  Jeanmaire D L, Van Duyne R P. Surface Raman Spectroelectrochemistry:Part I. Heterocyclic, Aromatic, and Aliphatic Amines Adsorbed on the Anodized Silver Electrode[J]. J Electroanal Chem Interfacial Electrochem, 1977,84(1):1-20. doi: 10.1016/S0022-0728(77)80224-6
4. [4]
  Albrecht M G, Creighton J A. Anomalously Intense Raman Spectra of Pyridine at a Silver Electrode[J]. J Am Chem Soc, 1977,99(15):5215-5217. doi: 10.1021/ja00457a071
5. [5]
  Ding S Y, You E M, Tian Z Q. Electromagnetic Theories of Surface-Enhanced Raman Spectroscopy[J]. Chem Soc Rev, 2017,46(13):4042-4076. doi: 10.1039/C7CS00238F
6. [6]
  Bilmes S A, Rubim J C, Otto A. SERS from Pyridine Adsorbed on Electrodispersed Platinum Electrodes[J]. Chem Phys Lett, 1989,159(1):89-96.
7. [7]
  Bryant M A, Joa S L, Pemberton J E. Raman Scattering from Monolayer Films of Thiophenol and 4-Mercaptopyridine at Platinum Surfaces[J]. Langmuir, 1992,8(3):753-756. doi: 10.1021/la00039a002
8. [8]
  Maeda T, Sasaki Y, Horie C. Raman Study of Electrochemical Reactions of a Pt Electrode in H₂SO₄ Solution[J]. J Electron Spectrosc Relat Phenom, 1993,64(1):381-389.
9. [9]
  Pettinger B, Tiedemann U. Surface Raman Spectroscopy at Pt Electrodes[J]. J Electroanal Chem Interfacial Electrochem, 1987,228(1):219-228.
10. [10]
  Shannon C, Campion A. Unenhanced Raman Scattering as an in situ Probe of the Electrode-Electrolyte Interface:4-Cyanopyridine Adsorbed on a Rhodium Electrode[J]. J Phys Chem, 1988,92(6):1385-1387. doi: 10.1021/j100317a002
11. [11]
  Yamada H, Yamamoto Y. Surface Enhanced Raman Scattering(SERS) of Chemisorbed Species on Various Kinds of Metals and Semiconductors[J]. Surf Sci, 1983,134(1):71-90. doi: 10.1016/0039-6028(83)90312-6
12. [12]
  Tian Z Q, Ren B, Wu D Y. Surface-Enhanced Raman Scattering:From Noble to Transition Metals and from Rough Surfaces to Ordered Nanostructures[J]. J Phys Chem B, 2002,106(37):9463-9483. doi: 10.1021/jp0257449
13. [13]
  Cao P G, Yao J L, Ren B. Surface-Enhanced Raman Scattering from Bare Fe Electrode Surfaces[J]. Chem Phys Lett, 2000,316(1):1-5.
14. [14]
  Gao J S, Tian Z Q. Surface Raman Spectroscopic Studies of Ruthenium, Rhodium and Palladium Electrodes Deposited on Glassy Carbon Substrates[J]. Spectrochim Acta, Part A, 1997,53(10):1595-1600. doi: 10.1016/S1386-1425(96)01855-0
15. [15]
  Ren B, Lin X F, Yan J W. Electrochemically Roughened Rhodium Electrode as a Substrate for Surface-Enhanced Raman Spectroscopy[J]. J Phys Chem B, 2003,107(4):899-902. doi: 10.1021/jp026862z
16. [16]
  Tian Z Q, Ren B, Mao B W. Extending Surface Raman Spectroscopy to Transition Metal Surfaces for Practical Applications.1.Vibrational Properties of Thiocyanate and Carbon Monoxide Adsorbed on Electrochemically Activated Platinum Surfaces[J]. J Phys Chem B, 1997,101(8):1338-1346. doi: 10.1021/jp962049q
17. [17]
  Tian Z Q, Ren B. Adsorption and Reaction at Electrochemical Interfaces as Probed by Surface-Enhanced Raman Spectroscopy[J]. Annu Rev Phys Chem, 2004,55(1):197-229. doi: 10.1146/annurev.physchem.54.011002.103833
18. [18]
  Yao J L, Tang J, Wu D Y. Surface Enhanced Raman Scattering from Transition Metal Nano-Wire Array and the Theoretical Consideration[J]. Surf Sci, 2002,514(1):108-116.
19. [19]
  REN Bin, TIAN Zhongqun. The Progress in Surface-enhanced Raman Spectroscopy[J]. Mod Instrum Med Treat, 2004,10(5):1-8.
20. [20]
  Kelly K L, Coronado E, Zhao L L. The Optical Properties of Metal Nanoparticles:The Influence of Size, Shape, and Dielectric Environment[J]. J Phys Chem B, 2003,107(3):668-677. doi: 10.1021/jp026731y
21. [21]
  Tian Z Q, Yang Z L, Ren B. Surface-Enhanced Raman Scattering from Transition Metals with Special Surface Morphology and Nanoparticle Shape[J]. Faraday Discuss, 2006,132:159-170. doi: 10.1039/B507773G
22. [22]
  McLellan J M, Xiong Y J, Hu M. Surface-Enhanced Raman Scattering of 4-Mercaptopyridine on Thin Films of Nanoscale Pd Cubes, Boxes, and Cages[J]. Chem Phys Lett, 2006,417(1):230-234.
23. [23]
  Van Duyne R P, Haushalter J P. Surface-Enhanced Raman Spectroscopy of Adsorbates on Semiconductor Electrode Surfaces:Tris(Bipyridine) Ruthenium(Ⅱ) Adsorbed on Silver-Modified n-Gallium Arsenide(100)[J]. J Phys Chem, 1983,87(16):2999-3003. doi: 10.1021/j100239a004
24. [24]
  Van Duyne R P, Haushalter J P, Janik-Czachor M. Surface-Enhanced Resonance Raman Spectroscopy of Adsorbates on Semiconductor Electrode Surfaces.2.In Situ Studies of Transition Metal(Iron and Ruthenium) Complexes on Silver/Gallium Arsenide and Silver/Silicon[J]. J Phys Chem, 1985,89(19):4055-4061. doi: 10.1021/j100265a026
25. [25]
  Fleischmann M, Tian Z Q, Li L J. Raman Spectroscopy of Adsorbates on Thin Film Electrodes Deposited on Silver Substrates[J]. J Electroanal Chem Interfacial Electrochem, 1987,217(2):397-410. doi: 10.1016/0022-0728(87)80231-0
26. [26]
  Leung L W H, Weaver M J. Extending Surface-Enhanced Raman Spectroscopy to Transition-Metal Surfaces:Carbon Monoxide Adsorption and Electrooxidation on Platinum-and Palladium-Coated Gold Electrodes[J]. J Am Chem Soc, 1987,109(17):5113-5119. doi: 10.1021/ja00251a011
27. [27]
  Leung L W H, Weaver M J. Adsorption and Electrooxidation of Carbon Monoxide on Rhodium-and Ruthenium-Coated Gold Electrodes as Probed by Surface-Enhanced Raman Spectroscopy[J]. Langmuir, 1988,4(5):1076-1083. doi: 10.1021/la00083a002
28. [28]
  Leung L W H, Weaver M J. Extending the Metal Interface Generality of Surface-Enhanced Raman Spectroscopy:Underpotential Deposited Layers of Mercury, Thallium, and Lead on Gold Electrodes[J]. J Electroanal Chem Interfacial Electrochem, 1987,217(2):367-384. doi: 10.1016/0022-0728(87)80229-2
29. [29]
  Mengoli G, Musiani M M, Fleischman M. Enhanced Raman Scattering from Iron Electrodes[J]. Electrochim Acta, 1987,32(8):1239-1245. doi: 10.1016/0013-4686(87)80042-7
30. [30]
  Park S, Yang P, Corredor P. Transition Metal-Coated Nanoparticle Films:Vibrational Characterization with Surface-Enhanced Raman Scattering[J]. J Am Chem Soc, 2002,124(11):2428-2429. doi: 10.1021/ja017406b
31. [31]
  Hu J W, Zhang Y, Li J F. Synthesis of Au@Pd Core-Shell Nanoparticles with Controllable Size and Their Application in Surface-Enhanced Raman Spectroscopy[J]. Chem Phys Lett, 2005,408(4):354-359.
32. [32]
  Lu L H, Sun G Y, Zhang H J. Fabrication of Core-Shell Au-Pt Nanoparticle Film and Its Potential Application as Catalysis and SERS Substrate[J]. J Mater Chem, 2004,14(6):1005-1009. doi: 10.1039/b314868h
33. [33]
  Tian Z Q, Ren B, Li J F. Expanding Generality of Surface-Enhanced Raman Spectroscopy with Borrowing SERS Activity Strategy[J]. Chem Commun, 2007,34(34):3514-3534.
34. [34]
  Wessel J. Surface-Enhanced Optical Microscopy[J]. J Opt Soc Am B, 1985,2(9):1538-1541. doi: 10.1364/JOSAB.2.001538
35. [35]
  Anderson M S. Locally Enhanced Raman Spectroscopy with an Atomic Force Microscope[J]. Appl Phys Lett, 2000,76(21):3130-3132. doi: 10.1063/1.126546
36. [36]
  Hayazawa N, Inouye Y, Sekkat Z. Metallized Tip Amplification of Near-Field Raman Scattering[J]. Opt Commun, 2000,183(1):333-336.
37. [37]
  Pettinger B, Picardi G, Schuster R. Surface Enhanced Raman Spectroscopy:Towards Single Molecular Spectroscopy[J]. Electrochemistry, 2000,68(12):942-949.
38. [38]
  St ckle R M, Suh Y D, Deckert V. Nanoscale Chemical Analysis by Tip-Enhanced Raman Spectroscopy[J]. Chem Phys Lett, 2000,318(1):131-136.
39. [39]
  Li J F, Huang Y F, Ding Y. Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy[J]. Nature, 2010,464:392-395. doi: 10.1038/nature08907
40. [40]
  Li J F, Zhang Y J, Ding S Y. Core-Shell Nanoparticle-Enhanced Raman Spectroscopy[J]. Chem Rev, 2017,117(7):5002-5069. doi: 10.1021/acs.chemrev.6b00596
41. [41]
  REN Bin, WANG Xi. Tip-enhanced Raman Spectroscopy-Technique, Applications and Perspectives[J]. Chinese J Light Scatt, 2006,18(4):288-296. doi: 10.3969/j.issn.1004-5929.2006.04.001
42. [42]
  Zhang R, Zhang Y, Dong Z C. Chemical Mapping of a Single Molecule by Plasmon-Enhanced Raman Scattering[J]. Nature, 2013,498:82-86. doi: 10.1038/nature12151
43. [43]
  Jiang S, Zhang Y, Zhang R. Distinguishing Adjacent Molecules on a Surface Using Plasmon-Enhanced Raman Scattering[J]. Nat Nanotechnol, 2015,10:865-869. doi: 10.1038/nnano.2015.170
44. [44]
  Zhong J H, Jin X, Meng L Y. Probing the Electronic and Catalytic Properties of a Bimetallic Surface with 3 nm Resolution[J]. Nat Nanotechnol, 2016,12:132-136. doi: 10.1038/nnano.2016.241
45. [45]
  Zeng Z C, Huang S C, Wu D Y. Electrochemical Tip-Enhanced Raman Spectroscopy[J]. J Am Chem Soc, 2015,137(37):11928-11931. doi: 10.1021/jacs.5b08143
46. [46]
  Li C Y, Dong J C, Jin X. In Situ Monitoring of Electrooxidation Processes at Gold Single Crystal Surfaces Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy[J]. J Am Chem Soc, 2015,137(24):7648-7651. doi: 10.1021/jacs.5b04670
47. [47]
  Zhang H, Wang C, Sun H L. In Situ Dynamic Tracking of Heterogeneous Nanocatalytic Processes by Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy[J]. Nat Commun, 2017,815447. doi: 10.1038/ncomms15447
48. [48]
  Zhang H, Zhang X G, Wei J. Revealing the Role of Interfacial Properties on Catalytic Behaviors by in situ Surface-Enhanced Raman Spectroscopy[J]. J Am Chem Soc, 2017,139(30):10339-10346. doi: 10.1021/jacs.7b04011
49. [49]
  Li J F, Anema J R, Wandlowski T. Dielectric Shell Isolated and Graphene Shell Isolated Nanoparticle Enhanced Raman Spectroscopies and Their Applications[J]. Chem Soc Rev, 2015,44(23):8399-8409. doi: 10.1039/C5CS00501A
50. [50]
  Ding S Y, Yi J, Li J F. Nanostructure-Based Plasmon-Enhanced Raman Spectroscopy for Surface Analysis of Materials[J]. Nat Rev Mater, 2016,116021. doi: 10.1038/natrevmats.2016.21
51. [51]
  Liu Y, Hu Y, Zhang J. Few-Layer Graphene-Encapsulated Metal Nanoparticles for Surface-Enhanced Raman Spectroscopy[J]. J Phys Chem C, 2014,118(17):8993-8998. doi: 10.1021/jp500751a
52. [52]
  Huang Y P, Huang S C, Wang X J, et al. Shell-Isolated Tip-Enhanced Raman and Fluorescence Spectroscopy[J]. Angew Chem Int Ed, DOI: 10.1002/anie.201802892.
53. [53]
  Xu J, Zhang Y J, Yin H. Shell-Isolated Nanoparticle-Enhanced Raman and Fluorescence Spectroscopies:Synthesis and Applications[J]. Adv Opt Mater, 2018,61701069. doi: 10.1002/adom.v6.4
54. [54]
  Aroca R F, Ross D J, Domingo C. Surface-Enhanced Infrared Spectroscopy[J]. Appl Spectrosc, 2004,58(11):324A-338A. doi: 10.1366/0003702042475420
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