Citation: FAN Zhenzhen, FAN Lifang, DONG Chuan. Synthesis of Iodine Oxygen Bismuth/Titanium Dioxide Nanorod Arrays Composite and Photoelectrochemical Detection of Bisphenol A[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 834-841. doi: 10.11944/j.issn.1000-0518.2018.07.180005 shu

Synthesis of Iodine Oxygen Bismuth/Titanium Dioxide Nanorod Arrays Composite and Photoelectrochemical Detection of Bisphenol A

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Corresponding author: DONG Chuan, dc@sxu.edu.cn
Received Date: 8 January 2018
Revised Date: 26 February 2018
Accepted Date: 22 March 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.21707082, No.21575084), the Natural Science Foundation of Shanxi Province, China(No.201601D202008)the National Natural Science Foundation of China 21575084, the Natural Science Foundation of Shanxi Province, China 201601D202008the National Natural Science Foundation of China 21707082

Figures(8)

Iodine oxygen bismuth/titanium dioxide nanorod arrays(BiOI/TiO₂ NRAs) composite was synthesized in situ on fluorine-doped tin oxide-coated glass(FTO) substrate by simple two-step hydrothermal method.The composite was characterized by scanning electron microscope and X-ray diffraction.The photoelectrochemical(PEC) behaviors were studied using current-time curve.The combination of BiOI with TiO₂ NRAs extends effectively the adsorption of TiO₂ to visible region, and the formed p-n heterojunction could contribute to the spatial charge separation as well as the enhanced photocatalytic activity.The PEC sensing platform fabricated by using this composite was applied for detection of bisphenol A(BPA) via the oxidation of BPA by the consumption of photogenerated holes during PEC reaction.Under 420 nm irradiation, current-time curve was used for sensitive detection of BPA at applied potential of 0.0 V, a wide linear work range from 0.0047 to 14.7 μmol/L was obtained with a low detection limit of 0.93 nmol/L(S/N=3).The developed PEC sensor exhibits high sensitivity, good stability and reproducibility.This sensor was also used to evaluate the level of BPA in real samples with good recovery from 98.0% to 107.1%.
- photoelectrochemical,
- bisphenol A,
- titanium dioxide nanorod arrays,
- Iodine oxygen bismuth
1. [1]
  Rubin B S. Bisphenol A:An Endocrine Disruptor with Widespread Exposure and Multiple Effects[J]. J Steroid Biochem Mol Biol, 2011,127(1/2):27-34.
2. [2]
  Alonso-Magdalena P, Ropero A B, Soriano S. Bisphenol-A Acts as a Potent Estrogen via Non-classical Estrogen Triggered Pathways[J]. Mol Cell Endocrinol, 2012,355(2):201-207. doi: 10.1016/j.mce.2011.12.012
3. [3]
  Perez-Lobato R, Mustieles V, Calvente I. Exposure to Bisphenol A and Behavior in School-Age Children[J]. Neuro Toxicol, 2016,53:12-19.
4. [4]
  Miao M H, Yuan W, Zhu G P. In Utero Exposure to Bisphenol-A and Its Effect on Birth Weight of Offspring[J]. Reprod Toxicol, 2011,32(1):64-68. doi: 10.1016/j.reprotox.2011.03.002
5. [5]
  Chen J F, Xiao Y Y, Gai Z X. Reproductive Toxicity of Low Level Bisphenol A Exposures in a Two-Generation Zebrafish Assay:Evidence of Male-specific Effects[J]. Aquat Toxicol, 2015,169:204-214. doi: 10.1016/j.aquatox.2015.10.020
6. [6]
  Soto A M, Sonnenschein C. Environmental Causes of Cancer:Endocrine Disruptors as Carcinogens[J]. Nat Rev Endocrinol, 2010,6(7):363-370. doi: 10.1038/nrendo.2010.87
7. [7]
  Devadoss A, Sudhagar P, Terashima C K. Photoelectrochemical Biosensors:New Insights into Promising Photoelectrodes and Signal Amplification Strategies[J]. J Photochem Photobiol C, 2015,24:43-63. doi: 10.1016/j.jphotochemrev.2015.06.002
8. [8]
  Wu X L, Wang L B, Ma W. A Simple, Sensitive, Rapid and Specific Detection Method for Bisphenol A Based on Fluorescence Polarization Immunoassay[J]. Immunol Invest, 2016,41(1):38-50.
9. [9]
  Braunrath R, Podlipna D, Padlesak S. Determination of Bisphenol A in Canned Foods by Immunoaffinity Chromatography, HPLC, and Fluorescence Detection[J]. J Agric Food Chem, 2005,53(23):8911-8917. doi: 10.1021/jf051525j
10. [10]
  Jiao Y N, Ding L, Fu S L. Determination of Bisphenol A, Bisphenol F and Their Diglycidyl Ethers in Environmental Water by Solid Phase Extraction Using Magnetic Multiwalled Carbon Nanotubes Followed by GC-MS/MS[J]. Anal Methods, 2012,4(1):291-298. doi: 10.1039/C1AY05433C
11. [11]
  Yi B, Kim C, Yang M. Biological Monitoring of Bisphenol A with HLPC/FLD and LC/MS/MS Assays[J]. J Chromatogr B, 2010,878(27):2606-2610. doi: 10.1016/j.jchromb.2010.02.008
12. [12]
  Zhao W W, Xu J J, Chen H Y. Photoelectrochemical Bioanalysis:The State of the Art[J]. Chem Soc Rev, 2015,44(3):729-741. doi: 10.1039/C4CS00228H
13. [13]
  Zhao W W, Xu J J, Chen H Y. Photoelectrochemical DNA Biosensors[J]. Chem Rev, 2014,114(15):7421-7441. doi: 10.1021/cr500100j
14. [14]
  Tang J, Zhang Y Y, Kong B. Solar-Driven Photoelectrochemical Probing of Nanodot/Nanowire/Cell Interface[J]. Nano Lett, 2014,14(5):2702-2708. doi: 10.1021/nl500608w
15. [15]
  Macwan D P, Dave P N, Chaturvedi S. A Review on Nano-TiO₂ Sol-Gel Type Syntheses and Its Applications[J]. J Mater Sci, 2011,46(11):3669-3686. doi: 10.1007/s10853-011-5378-y
16. [16]
  Wang X D, Li Z D, Shi J. One-dimensional Titanium Dioxide Nanomaterials:Nanowires, Nanorods, and Nanobelts[J]. Chem Rev, 2014,114(19):9346-9384. doi: 10.1021/cr400633s
17. [17]
  Xiao X, Zhang W D. Facile synthesis of Nanostructured BiOI Microspheres with High Visible Light-induced Photocatalytic Activity[J]. J Mater Chem, 2010,20(28):5866-5870. doi: 10.1039/c0jm00333f
18. [18]
  Lei Y Q, Wang G H, Song S Y. Room Temperature, Template-Free Synthesis of BiOI Hierarchical Structures:Visible-Light Photocatalytic and Electrochemical Hydrogen Storage Properties[J]. Dalton Trans, 2010,39(13):3273-3278. doi: 10.1039/b922126c
19. [19]
  Zhang L, Ruan Y F, Liang Y Y. Bismuth Oxyiodide Couples with Glucose Oxidase:A Special Synergized Dual-catalysis Mechanism for Photoelectrochemical Enzymatic Bioanalysis[J]. Appl Mater Interfaces, 2018,10(4):3372-3379. doi: 10.1021/acsami.7b17647
20. [20]
  Zhang X, Zhang L Z, Xie T F. Low-temperature Synthesis and High Visible-light-induced Photocatalytic Activity of BiOI/TiO₂ Heterostructures[J]. J Phys Chem C, 2009,113(17):7371-7378. doi: 10.1021/jp900812d
21. [21]
  Liao C X, Ma Z J, Dong G P. BiOI Nanosheets Decorated TiO₂ Nanofiber:Tailoring Water Purification Performance of Photocatalyst in Structural and Photo-Responsivity Aspects[J]. Appl Surf Sci, 2014,314:481-489. doi: 10.1016/j.apsusc.2014.07.032
22. [22]
  Liu B, Aydil E S. Growth of Oriented Single-Crystalline Rutile TiO₂ Nanorods on Transparent Conducting Substrates for Dye-sensitized Solar Cells[J]. J Am Chem Soc, 2009,131(11):3985-3990. doi: 10.1021/ja8078972
23. [23]
  Wang L Y, Daoud W A. BiOI/TiO₂-nanorod Array Heterojunction Solar Cell:Growth, Charge Transport Kinetics and Photoelectrochemical Properties[J]. Appl Surf Sci, 2015,324:532-537. doi: 10.1016/j.apsusc.2014.10.110
24. [24]
  Chen H P, Tang N, Chen M. Endothelialization of TiO₂ Nanorods Coated with Ultrathin Amorphous Carbon Films[J]. Nanoscale Res Lett, 2016,11:145-153. doi: 10.1186/s11671-016-1358-0
25. [25]
  Zhao W W, Shan S, Ma Z Y. Acetylcholine Esterase Antibodies on BiOI Nanoflakes/TiO₂ Nanoparticles Electrode:A Case of Application for General Photoelectrochemical Enzymatic Analysis[J]. Anal Chem, 2013,85(24):11686-11690. doi: 10.1021/ac403691a
26. [26]
  Yu C M, Gou L L, Zhou X H. Chitosan-Fe₃O₄ Nanocomposite Based Electrochemical Sensors for the Determination of Bisphenol A[J]. Electrochim Acta, 2011,56(25):9056-9063. doi: 10.1016/j.electacta.2011.05.135
27. [27]
  Lin Y Q, Liu K Y, Liu C Y. Electrochemical Sensing of Bisphenol A Based on Polyglutamic Acid/Amino-Functionalised Carbon Nanotubes Nanocomposite[J]. Electrochim Acta, 2014,133:492-500. doi: 10.1016/j.electacta.2014.04.095
28. [28]
  Hu L S, Fong C C, Zhang X M. Au Nanoparticles Decorated TiO₂ Nanotube Arrays as a Recyclable Sensor for Photoenhanced Electrochemical Detection of Bisphenol A[J]. Environ Sci Technol, 2016,50(8):4430-4438. doi: 10.1021/acs.est.5b05857
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