Citation: DONG Li, LIU Xiangdong, XIONG Zhengrong, YANG Yuming. Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 776-780. doi: 10.11944/j.issn.1000-0518.2018.07.170331 shu

Preparation of Macromolecular Ultra-violet Absorber and Its Application in Poly(vinylidene fluoride)

a.
Laboratory of Polymer Composites Engineering, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: YANG Yuming, ymyang@ciac.ac.cn
Received Date: 12 September 2017
Revised Date: 19 October 2017
Accepted Date: 10 November 2017

Figures(6)

The macromolecular ultraviolet(UV) absorber P(MMA-co-BPMA) was synthesized by copolymerization of 2-hydroxy-4-(3-methacryloxy-2-hydroxylpropoxy) benzophenone(BPMA) and methylmethacrylate(MMA) through atom transfer radical polymerization(ATRP). The UV-absorbing poly(vinylidene fluoride)(PVDF) composite membranes were made by blend coating. The structure and property of BPMA and P(MMA-co-BPMA) were characterized by nuclear magnetic resonance spectroscopy(NMR), gel permeation chromatography(GPC) and differential scanning calorimeter(DSC). UV absorbing property of the obtained composite membranes was investigated by UV-Vis spectroscopy. The results demonstrate that the relative molecular mass polydispersity index(PDI) of P(MMA-co-BPMA) is 1.11. When the mass fraction of BPMA is 0.68%, the UV transmittance of P(MMA-co-BPMA)/PVDF composite membrane decreases to less than 0.4% in the range of 200~345 nm. In addition, copolymerization of the UV absorber effectively prevents the out-migration as demonstrated in the extraction experiment.
- ultra-violet absorbing,
- poly(vinylidene fluoride),
- copolymerization,
- blends
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1.
沈阳化工大学材料科学与工程学院沈阳 110142