Citation: YANG Chunlin, FENG Yonglan, ZHANG Fuxing, YU Jiangxi, JIANG Wujiu, KUANG Daizhi. Syntheses, Struture and Herbicidal Activity of Bis(substituted salicylaldehyde) Carbohydrazide n-Butyltin Complexes[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 795-801. doi: 10.11944/j.issn.1000-0518.2018.07.170326 shu

Syntheses, Struture and Herbicidal Activity of Bis(substituted salicylaldehyde) Carbohydrazide n-Butyltin Complexes

a.
Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China
b.
College of Chemistry, Xiangtan University, Xiangtan, Hunan 411100, China

Corresponding author: KUANG Daizhi, hnkcq@qq.com
Received Date: 11 September 2017
Revised Date: 25 October 2017
Accepted Date: 28 November 2017

Fund Project: Supported by the Innovation Platform Open Fund of Hu′nan Provincial Education Department(No.16K011, No.14K014), the Natural Science Foundation of Hu′nan Province(No.13JJ3112)the Innovation Platform Open Fund of Hu′nan Provincial Education Department 16K011the Natural Science Foundation of Hu′nan Province 13JJ3112the Innovation Platform Open Fund of Hu′nan Provincial Education Department 14K014

Figures(3)

Four n-butyltin complexes, (n-BuSn)₂Cl₃(OH₂)[(2-OH, R)PhCH=NNH]₂CX[R:4-NEt₂, X:O(A1); R:4-NEt₂, X:S(A2); R:3, 5-(t-Bu)₂, X:O(A3); R:3, 5-(t-Bu)₂, X:S(A4)], were obtained by microwave-assisted solvothermal reaction of n-butyltintrichloride(n-BuSnCl₃) with bis(4-diethylamino or 3, 5-di-t-butyl salicylaldehyde)carbohydrazide and thiocarbohydrazide in methanol environments, which were characterized by elemental analysis, IR, ¹H NMR, and ¹³C NMR spectra.The crystal structure of complex A2 shows a binuclear hexacoordinated distorted octahedral configuration.The ligands and their butyltin complexes inhibit the growth of plants, such as Portulaca oleracea, Amaranthus spinosus, Brassica campestris ssp.chinensis var.Utilis, Amaranthus tricolor and Cassia tora.Complexes A1, A2 have a broad range of growth inhibition activity, while complexes A3 and A4 have selective inhibitory activity.They can be used as candidate herbicides for weed growth inhibition.
- bis(substituted salicylaldehyde) carbohydrazide butyltin complex,
- crystal struture,
- herbicidal activity
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沈阳化工大学材料科学与工程学院沈阳 110142