Citation: SU Wenrou, CHEN Ji, DENG Yuefeng, YANG Maohua, LIU Chuanying. Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 802-811. doi: 10.11944/j.issn.1000-0518.2018.07.170321 shu

Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin

SU Wenrou ^a,b ,
CHEN Ji ^a,, ,
DENG Yuefeng ^a ,
YANG Maohua ^a ,
LIU Chuanying ^a,b

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: CHEN Ji, jchen@ciac.ac.cn
Received Date: 5 September 2017
Revised Date: 10 October 2017
Accepted Date: 9 November 2017

Fund Project: the National Natural Science Foundation of China 61106017Supported by the National Natural Science Foundation of China(No.61106017)

Figures(11)

The adsorption process of anion exchange resin to organphosphorus extractant in water was explored in this work. By comparing the removal of P507(2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester) in water with different anion exchange resins, it is found that D201-OH(macroporous strong basic anion exchange resin) has the strongest ability to remove P507 from water, and the removal rate can reach to 99.24%. Secondly, at pH=1.0, the adsorption of P507 on D201-OH is mainly molecular adsorption and its adsorption isotherm is better fit to the Langmuir model; at pH=5.0, the anion exchange reaction is dominant and its adsorption isotherm is more suitable for the Freundlich model. Furthermore, the adsorption capacity of D201-OH to P507 reaches 99.8% of which in the adsorption equilibrium in 20 min. Kinetic study shows that the pseudo-first-order model(R² > 0.99) exhibits a better fit to describe the experimental data and the adsorption rate may be controlled mainly by the film diffusion. Moreover, the adsorption capacity of D201-OH remains above 93% after eight cycles of adsorption-desorption. In summary, D201-OH is an excellent adsorbent for organphosphorus extractants with high stability in the repeated cycle. Therefore, it can be used to recover organphosphorus extractant in the practical production process.
- anion exchange resin,
- organphosphorus extractant,
- adsorption mechanism,
- cycle experiment
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