Citation: SU Wenrou, CHEN Ji, DENG Yuefeng, YANG Maohua, LIU Chuanying. Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 802-811. doi: 10.11944/j.issn.1000-0518.2018.07.170321 shu

Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin

SU Wenrou ^a,b ,
CHEN Ji ^a,, ,
DENG Yuefeng ^a ,
YANG Maohua ^a ,
LIU Chuanying ^a,b

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: CHEN Ji, jchen@ciac.ac.cn
Received Date: 5 September 2017
Revised Date: 10 October 2017
Accepted Date: 9 November 2017

Fund Project: the National Natural Science Foundation of China 61106017Supported by the National Natural Science Foundation of China(No.61106017)

Figures(11)

The adsorption process of anion exchange resin to organphosphorus extractant in water was explored in this work. By comparing the removal of P507(2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester) in water with different anion exchange resins, it is found that D201-OH(macroporous strong basic anion exchange resin) has the strongest ability to remove P507 from water, and the removal rate can reach to 99.24%. Secondly, at pH=1.0, the adsorption of P507 on D201-OH is mainly molecular adsorption and its adsorption isotherm is better fit to the Langmuir model; at pH=5.0, the anion exchange reaction is dominant and its adsorption isotherm is more suitable for the Freundlich model. Furthermore, the adsorption capacity of D201-OH to P507 reaches 99.8% of which in the adsorption equilibrium in 20 min. Kinetic study shows that the pseudo-first-order model(R² > 0.99) exhibits a better fit to describe the experimental data and the adsorption rate may be controlled mainly by the film diffusion. Moreover, the adsorption capacity of D201-OH remains above 93% after eight cycles of adsorption-desorption. In summary, D201-OH is an excellent adsorbent for organphosphorus extractants with high stability in the repeated cycle. Therefore, it can be used to recover organphosphorus extractant in the practical production process.
- anion exchange resin,
- organphosphorus extractant,
- adsorption mechanism,
- cycle experiment
1. [1]
  Grandell L, Lehtilä A, Kivinen M. Role of Critical Metals in the Future Markets of Clean Energy Technologies[J]. Renew Energ, 2016,95:53-62. doi: 10.1016/j.renene.2016.03.102
2. [2]
  Su W R, Chen J, Jing Y. Aqueous Partition Mechanism of Organophosphorus Extractants in Rare Earths Extraction[J]. Ind Eng Chem Res, 2016,55(30):8424-8431. doi: 10.1021/acs.iecr.6b01709
3. [3]
  Zhu X Y, Li B, Yang J. Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-based MOFs of UiO-67[J]. Adv Colloid Interface Sci, 2014,7(1):223-231.
4. [4]
  Islam M A, Sakkas V, Albanis T A. Application of Statistical Design of Experiment with Desirability Function for the Removal of Organophosphorus Pesticide from Aqueous Solution by Low-cost Material[J]. J Hazard Mater, 2009,170(1):230-238. doi: 10.1016/j.jhazmat.2009.04.106
5. [5]
  Chen L, Chen J, Jing Y. Comprehensive Appraisal and Application of Novel Extraction System for Heavy Rare Earth Separation on the Basis of Coordination Equilibrium Effect[J]. Hydrometallurgy, 2016,165:351-357. doi: 10.1016/j.hydromet.2015.12.007
6. [6]
  Jing Y, Chen J, Chen L. Extraction Behaviors of Heavy Rare Earths with Organophosphoric Extractants:The Contribution of Extractant Dimer Dissociation, Acid Ionization, and Complexation. A Quantum Chemistry Study[J]. J Phys Chem B, 2017,121(12):2531-2543. doi: 10.1021/acs.jpca.7b01444
7. [7]
  Guivarch E, Oturan N, Oturan M A. Removal of Organophosphorus Pesticides from Water by Electrogenerated Fenton's Reagent[J]. Environ Chem Lett, 2003,1(3):165-168. doi: 10.1007/s10311-003-0029-4
8. [8]
  Naushad M, Alothman Z, Khan M. Equilibrium, Kinetics and Thermodynamic Studies for the Removal of Organophosphorus Pesticide Using Amberlyst-15 Resin:Quantitative Analysis by Liquid Chromatography-Mass Spectrometry[J]. J Ind Eng Chem, 2014,20(6):4393-4400. doi: 10.1016/j.jiec.2014.02.006
9. [9]
  Cycoń M, Żmijowska A, Wójcik M. Biodegradation and Bioremediation Potential of Diazinon-degrading Serratia marcescens to Remove Other Organophosphorus Pesticides from Soils[J]. J Environ Manage, 2013,117:7-16. doi: 10.1016/j.jenvman.2012.12.031
10. [10]
  Wei W, Du J J, Li J. Construction of Robust Enzyme Nanocapsules for Effective Organophosphate Decontamination, Detoxification, and Protection[J]. Adv Mater, 2013,25(15):2212-2218. doi: 10.1002/adma.201205138
11. [11]
  Ahmad A, Tan L, Shukor S A. Dimethoate and Atrazine Retention from Aqueous Solution by Nanofiltration Membranes[J]. J Hazard Mater, 2008,151(1):71-77. doi: 10.1016/j.jhazmat.2007.05.047
12. [12]
  Badawy M I, Ghaly M Y, Gad-Allah T A. Advanced Oxidation Processes for the Removal of Organophosphorus Pesticides from Wastewater[J]. Desalination, 2006,194(1/2/3):166-175.
13. [13]
  Tolosa I, Readman J W, Mee L D. Comparison of the Performance of Solid-phase Extraction Techniques in Recovering Organophosphorus and Organochlorine Compounds from Water[J]. J Chromatogr A, 1996,725(1):93-106. doi: 10.1016/0021-9673(95)00874-8
14. [14]
  Aksu Z. Determination of the Equilibrium, Kinetic and Thermodynamic Parameters of the Batch Biosorption of Nickel(Ⅱ) Ions onto Chlorella vulgaris[J]. Process Biochem, 2002,38(1):89-99.
15. [15]
  Li Y H, Di Z C, Ding J. Adsorption Thermodynamic, Kinetic and Desorption Studies of Pb²⁺ on Carbon Nanotubes[J]. Water Res, 2005,39(4):605-609. doi: 10.1016/j.watres.2004.11.004
16. [16]
  Halsey G D. The Role of Surface Heterogeneity in Adsorption[J]. Adv Catal, 1952,4:259-269.
17. [17]
  Erdem E, Çölgeçen G, Donat R. The Removal of Textile Dyes by Diatomite Earth[J]. J Colloid Interface Sci, 2005,282(2):314-319. doi: 10.1016/j.jcis.2004.08.166
18. [18]
  Zhu L L, Deng Y F, Zhang J P. Adsorption of Phenol from Water by N-Butylimidazolium Functionalized Strongly Basic Anion Exchange Resin[J]. J Colloid Interface Sci, 2011,364(2):462-468. doi: 10.1016/j.jcis.2011.08.068
19. [19]
  Onganer Y, Temur Ç. Adsorption Dynamics of Fe(Ⅲ) from Aqueous Solutions onto Activated Carbon[J]. J Colloid Interface Sci, 1998,205(2):241-244. doi: 10.1006/jcis.1998.5616
20. [20]
  Ho Y S, McKay G. Pseudo-second Order Model for Sorption Processes[J]. Process Biochem, 1999,34(5):451-465. doi: 10.1016/S0032-9592(98)00112-5
21. [21]
  Basha S, Murthy Z, Jha B. Sorption of Hg(Ⅱ) onto Carica papaya:Experimental Studies and Design of Batch Sorber[J]. Chem Eng J, 2009,147(2):226-234.
22. [22]
  Djeribi R, Hamdaoui O. Sorption of Copper(Ⅱ) from Aqueous Solutions by Cedar Sawdust and Crushed Brick[J]. Desalination, 2008,225(1/2/3):95-112.
23. [23]
  Boyd G, Adamson A, Myers Jr L. The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites.Ⅱ.Kinetics[J]. J Am Chem Soc, 1947,69(11):2836-2848. doi: 10.1021/ja01203a066
24. [24]
  Mohan D, Singh K P. Single- and Multi-component Adsorption of Cadmium and Zinc Using Activated Carbon Derived from Bagasse-An Agricultural Waste[J]. Water Res, 2002,36(9):2304-2318. doi: 10.1016/S0043-1354(01)00447-X
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