Citation: LI Suwen, ZHANG Xuewei, JIANG Yi, YUE Jinying, GUAN Cong. Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 812-817. doi: 10.11944/j.issn.1000-0518.2018.07.170295 shu

Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate

College of Science, Changchun Institute of Technology, Changchun 130012, China

Corresponding author: LI Suwen, lx_lsw@ccit.edu.cn
Received Date: 21 August 2017
Revised Date: 17 October 2017
Accepted Date: 1 December 2017

Fund Project: the Undergraduate Innovation and Entrepreneurship Training Program of Jilin Province 201611437001Supported by the National Natural Science Foundation of China(No.11304021), the Undergraduate Innovation and Entrepreneurship Training Program of Jilin Province(No.201611437001)the National Natural Science Foundation of China 11304021

Figures(5)

Uniform BaF₂:Tb³⁺ nanoparticles have been prepared by hydrothermal synthesis, and sodium salicylate(SS) sensitized BaF₂:Tb³⁺(SS-BaF₂:Tb³⁺) nanoparticles have been prepared by the ion exchange technique. Their structures, morphologies and photoluminescence properties were studied. A broad excitation band from 200 to 385 nm by monitoring ⁵D₄→⁷F₅ transition of Tb³⁺ at 547 nm in SS-BaF₂:Tb³⁺ nanoparticles was detected. Under excitation of the π-π^* electron transition absorption of salicylate, enhanced green emission of Tb³⁺ ions in SS-BaF₂:Tb³⁺ nanoparticles was observed due to the energy transfer from SS to Tb³⁺ ions by "antenna effect". The photoluminescence lifetimes of Tb³⁺ ions in SS sensitized nanoparticles were found to be longer than those in un-sensitized nanoparticles.
- sensitization,
- energy transfer,
- nanoparticles,
- photoluminescence properties
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Sensitized Luminescence of Terbium(Ⅲ) in BaF2:Tb3+ Nanoparticles by Salicylate

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Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate