Citation: LI Suwen, ZHANG Xuewei, JIANG Yi, YUE Jinying, GUAN Cong. Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 812-817. doi: 10.11944/j.issn.1000-0518.2018.07.170295 shu

Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate

College of Science, Changchun Institute of Technology, Changchun 130012, China

Corresponding author: LI Suwen, lx_lsw@ccit.edu.cn
Received Date: 21 August 2017
Revised Date: 17 October 2017
Accepted Date: 1 December 2017

Fund Project: the Undergraduate Innovation and Entrepreneurship Training Program of Jilin Province 201611437001Supported by the National Natural Science Foundation of China(No.11304021), the Undergraduate Innovation and Entrepreneurship Training Program of Jilin Province(No.201611437001)the National Natural Science Foundation of China 11304021

Figures(5)

Uniform BaF₂:Tb³⁺ nanoparticles have been prepared by hydrothermal synthesis, and sodium salicylate(SS) sensitized BaF₂:Tb³⁺(SS-BaF₂:Tb³⁺) nanoparticles have been prepared by the ion exchange technique. Their structures, morphologies and photoluminescence properties were studied. A broad excitation band from 200 to 385 nm by monitoring ⁵D₄→⁷F₅ transition of Tb³⁺ at 547 nm in SS-BaF₂:Tb³⁺ nanoparticles was detected. Under excitation of the π-π^* electron transition absorption of salicylate, enhanced green emission of Tb³⁺ ions in SS-BaF₂:Tb³⁺ nanoparticles was observed due to the energy transfer from SS to Tb³⁺ ions by "antenna effect". The photoluminescence lifetimes of Tb³⁺ ions in SS sensitized nanoparticles were found to be longer than those in un-sensitized nanoparticles.
- sensitization,
- energy transfer,
- nanoparticles,
- photoluminescence properties
1. [1]
  Stouwdam J W, Veggel F C J M van. Near-Infrared Emission of Redispersible Er³⁺, Nd³⁺, and Ho³⁺ Doped LaF₃ Nanoparticles[J]. Nano Lett, 2002,2:733-737. doi: 10.1021/nl025562q
2. [2]
  Zhang M F, Fan H, Xi B J. Synthesis, Characterization, and Luminescence Properties of Uniform Ln³⁺-Doped YF₃ Nanospindles[J]. J Phys Chem C, 2007,111:6652-6657. doi: 10.1021/jp068919d
3. [3]
  Metz P W, Marzahl D T, Majid A. Efficient Continuous Wave Laser Operation of Tb³⁺-doped Fluoride Crystals in the Green and Yellow Spectral Regions[J]. Laser Photonics Rev, 2016,10(2):335-344. doi: 10.1002/lpor.201500274
4. [4]
  Yang D M, Dai Y L, Liu J H. Ultra-small BaGdF₅-based Upconversion Nanoparticles as Drug Carriers and Multimodal Imaging Probes[J]. Biomaterials, 2014,35(6):2011-2023. doi: 10.1016/j.biomaterials.2013.11.018
5. [5]
  Suemune Y, Ikawa H. Thermal Conductivity of KMnF₃, KCoF₃, KNiF₃, and KZnF₃ Single Crystals[J]. J Phys Soc Jpn, 1964,19(9):1686-1690. doi: 10.1143/JPSJ.19.1686
6. [6]
  Quan Z W, Yang D M, Yang P P. Uniform Colloidal Alkaline Earth Metal Fluoride Nanocrystals:Nonhydrolytic Synthesis and Luminescence Properties[J]. Inorg Chem, 2008,47(20):9509-9571. doi: 10.1021/ic8014207
7. [7]
  Vicinelli V, Ceroni P, Maestri M. Luminescent Lanthanide Ions Hosted in a Fluorescent Polylysin Dendrimer. Antenna-Like Sensitization of Visible and Near-Infrared Emission[J]. J Am Chem Soc, 2002,124(22):6461-6468. doi: 10.1021/ja017672p
8. [8]
  Deun R van, Fias P, Nockemann P. Visible-Light-Sensitized Near-Infrared Luminescence from Rare-Earth Complexes of the 9-Hydroxyphenalen-1-one Ligand[J]. Inorg Chem, 2006,45(26):10416-10418. doi: 10.1021/ic0616277
9. [9]
  Gunnlaugsson T, Stomeo F. Recent Advances in the Formation of Luminescent Lanthanide Architectures and Self-assemblies from Structurally Defined Ligands[J]. Org Biomol Chem, 2007,5(4):1999-2009.
10. [10]
  Weissman S I. Intramolecular Energy Transfer the Fluorescence of Complexes of Europium[J]. J Chem Phys, 1942,10(4):214-217. doi: 10.1063/1.1723709
11. [11]
  Kaur G, Dwivedi Y, Rai S B. Synthesis, Structural, Thermal and Optical Studies of Rare Earth Coordinated Complex:Tb(Sal)₃Phen[J]. Mater Chem Phys, 2011,130(3):1351-1356. doi: 10.1016/j.matchemphys.2011.09.028
12. [12]
  Maji S, Viswanathan K S. Ligand-sensitized Fluorescence of Eu³⁺ Using Naphthalene Carboxylic Acids as Ligands[J]. J Lumin, 2008,128(8):1255-1261. doi: 10.1016/j.jlumin.2007.12.002
13. [13]
  GUO Dongcai, SHU Wangen, ZHANG Wei. Synthesis and Luminescence Property of Ternary Complexes of Terbium with Aromatic Carboxylic Acid and Acrylonitrile[J]. Chinese J Appl Chem, 2004,21(12):1323-1325. doi: 10.3969/j.issn.1000-0518.2004.12.028
14. [14]
  Zhang J, Shade C M, Chengelis D A. A Strategy to Protect and Sensitize Near-Infrared Luminescent Nd³⁺ and Yb³⁺:Organic Tropolonate Ligands for the Sensitization of Ln³⁺-Doped NaYF₄ Nanocrystals[J]. J Am Chem Soc, 2007,129(48):14834-14835. doi: 10.1021/ja074564f
15. [15]
  Cross M, May P S, Veggel F C J M van. Dipicolinate Sensitization of Europium Luminescence in Dispersible 5%Eu:LaF₃ Nanoparticles[J]. J Phys Chem C, 2010,114(35):14740-14747. doi: 10.1021/jp103366j
16. [16]
  Li S W, Zhang X, Hou Z Y. Enhanced Emission of Ultra-small-sized LaF₃:RE³⁺(RE=Eu, Tb) Nanoparticles Through 1, 2, 4, 5-Benzenetetracarboxylic Acid Sensitization[J]. Nanoscale, 2012,4(18):5619-5626. doi: 10.1039/c2nr31206a
17. [17]
  Li S W, Li X J, Jiang Y. Highly Luminescent Lanthanide Fluoride Nanoparticles Functionalized by Aromatic Carboxylates Acid[J]. RSC Adv, 2014,4:55100-55107. doi: 10.1039/C4RA09266J
18. [18]
  Lin J, Su Q. Luminescence and Energy Transfer of Rare Earth Metal Ions in Mg₂Y₈(SiO₄)₆O₂[J]. J Mater Chem, 1995,5(8):1151-1154. doi: 10.1039/jm9950501151
19. [19]
  Thomas K S, Singh S, Dieke G H. Energy Levels of Tb³⁺ in LaCl₃ and Other Chlorides[J]. J Chem Phys, 1963,38(9):2180-2190. doi: 10.1063/1.1733948
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Sensitized Luminescence of Terbium(Ⅲ) in BaF2:Tb3+ Nanoparticles by Salicylate

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Sensitized Luminescence of Terbium(Ⅲ) in BaF₂:Tb³⁺ Nanoparticles by Salicylate