Citation: HONG Feng, YIN Yueru, TIAN Yupeng, WU Jieying. A Novel Third-Order Non-Linear Optical Ruthenium(Ⅱ) Complex Based on Imidazo-phenanthroline Derivative: Design, Synthesis and DNA Binding Properties[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 818-824. doi: 10.11944/j.issn.1000-0518.2018.07.170290 shu

A Novel Third-Order Non-Linear Optical Ruthenium(Ⅱ) Complex Based on Imidazo-phenanthroline Derivative: Design, Synthesis and DNA Binding Properties

College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China

Corresponding author: WU Jieying, jywu1957@163.com
Received Date: 18 August 2017
Revised Date: 30 September 2017
Accepted Date: 24 November 2017

Fund Project: the National Natural Science Foundation of China 51672002Supported by the National Natural Science Foundation of China(No.51672002), Student Research Training Program of Anhui University(No.KYXL2016027)Student Research Training Program of Anhui University KYXL2016027

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A new D-π-A type two-photon absorption ligand(L) based on imidazo[4, 5-f] ^{[1, 10]} phenanthroline and its Ru(Ⅱ) complex(1) have been synthesized and characterized. The third-order nonlinear optical(NLO) properties of all compounds are studied by open/close aperture Z-scan techniques. The results reveal that complex 1 possesses larger third-order nonlinear susceptibility and two-photon absorption cross section than its free ligand L in the near infrared range. A reverse nonlinear optical refraction character takes place from self-defocusing to self-focusing response after complexation. Calf-thymus DNA binding properties combined with complex 1 are studied by UV-Vis absorption, DNA competitive binding with ethidium bromide, viscosity measurements, and circular dichrosim spectra. The results indicate that complex 1 binds to DNA via an intercalative mode. Therefore, the complex 1 with nonlinear optical properties can be used for bioimaging applications.
- phenanthroline,
- Ru(Ⅱ) complexes,
- third-order nonlinear optical property,
- DNA binding,
- two-photon absorption effect
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