Citation: HUANG Gang, ZHANG Hongwei, ZHANG Huanhuan, SHI Tongfei, XU Donghua. Influence of Graphene Oxide on the Rheological Properties of Poly(vinyl alcohol)/Borate Hydrogel[J]. Chinese Journal of Applied Chemistry, ;2018, 35(7): 767-775. doi: 10.11944/j.issn.1000-0518.2018.07.170273 shu

Influence of Graphene Oxide on the Rheological Properties of Poly(vinyl alcohol)/Borate Hydrogel

a.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
c.
Department of Food Science, Rutgers, The State University of New Jersey, 65 Dudley Road, New Brunswick, NJ 08901, USA

Corresponding author: XU Donghua, dhxu@ciac.ac.cn
Received Date: 8 August 2017
Revised Date: 24 August 2017
Accepted Date: 22 September 2017

Fund Project: the National Natural Science Foundation of China 21274152Supported by the National Natural Science Foundation of China(No.21274152)

Figures(8)

The influence of graphene oxide(GO) on the linear and nonlinear rheological properties of poly(vinyl alcohol)(PVA)/borate hydrogel was explored in this work. Results of scanning electron microscopy, ¹¹B nuclear magnetic resonance and rheology reveal that elastically active points formed between dispersed GO sheets and PVA chains have enhanced plateau modulus(G₀), relaxation time(τ) and zero shear viscosity(η₀) of samples when the mass concentration of GO(ρ(GO)) is in the dilute concentration regime. As ρ(GO) is further increased to the semi-dilute concentration regime, part of cross-linkers is occupied by GO aggregation and exists as non-elastically active GO-borate-GO bond, then G₀, τ and η₀ of samples are decreased with ρ(GO). Under steady shear, the enhancement of viscosity in shear thickening regime always increases with ρ(GO) in different concentration regimes, which is related with the participation of oriented GO sheets to reorganization of the network.
- poly(vinyl alcohol)/borate hydrogel,
- grapheme oxide,
- shear thickening,
- rheology
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