Citation: ZHOU Yanfang, ZENG Ze, XIE Gang, JIAO Chenjie, ZHOU Yubing, ZHONG Rong. Synthesis and Photoinitiation Properties of Pentaerythritol Tetrabenzoyl Formate[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 652-658. doi: 10.11944/j.issn.1000-0518.2018.06.170228 shu

Synthesis and Photoinitiation Properties of Pentaerythritol Tetrabenzoyl Formate

ZHOU Yanfang ^a ,
ZENG Ze ^a ,
XIE Gang ^a ,
JIAO Chenjie ^a ,
ZHOU Yubing ^a ,
ZHONG Rong ^a,b,,

a.
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China
b.
Jiangxi Province Engineering Technology Research Center of Papermaking Chemicals, Nanchang Hangkong University, Nanchang 330063, China

Corresponding author: ZHONG Rong, zhongr@nchu.edu.cn
Received Date: 26 June 2017
Revised Date: 15 September 2017
Accepted Date: 5 December 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.21364008), the Science and Technology Conditions Platform Special Construction Funds in Jiangxi Province(No.20164BCD40098)the National Natural Science Foundation of China 21364008the Science and Technology Conditions Platform Special Construction Funds in Jiangxi Province 20164BCD40098

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The limit of small molecule photoinitiators to applications of food and medical materials due to the toxicity of its residual fragments can be solved by the macromolecular photoinitiators. In this paper, pentaerythritol tetrahydrobenzoylformate(PTF) was synthesized using benzoyl formic acid(BF) and pentaerythritol(PET) as raw materials by acid chloride method. The results of thermal analysis show that there is 15% mass loss at 225℃ for PTF and its thermal stability is better than that of 2-hydroxy-2-methyl-1-phenyl-1-propanone(1173 photoinitiator). The initial decomposition temperature and the temperature with the same mass loss for the photocurable coatings using PTF as the photoinitiator are 100℃ higher than those for coatings using 1173 photoinitiator. The results show that the maximum reaction rate is 0.037 s^-1, the final double bond conversion is 39.5%, and PTF has higher photoinduced activity than 1173 in the trimethylolpropane triacrylate(TMPTA) polymerization by light-differential scanning calorimetry. The residue content of PTF is only 5% of that of 1173 photoinitiator under the same experimental conditions.
- pentaerythritol tetraphenoylformate,
- ultraviolet curing,
- photoinitiation properties
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