Citation: SHI Jia, SONG Huangwang, ZHU Qidong, LIN Qiang, ZHU Linhua, LIU Yinghao, ZHONG Wanlin. Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 659-664. doi: 10.11944/j.issn.1000-0518.2018.06.170211 shu

Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China

Corresponding author: LIN Qiang, linqianggroup@163.com ZHU Linhua, zhulinhua1981@163.com
Received Date: 16 June 2017
Revised Date: 7 August 2017
Accepted Date: 1 September 2017

Fund Project: the Natural Science Foundation of Hainan Province 217108the Scientific and Technical Personnel Services Business Projects 2009GJE20014Supported by the Scientific and Technical Personnel Services Business Projects(No.2009GJE20014), the Natural Science Foundation of Hainan Province(No.217108)

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The addition of co-complexing agent is beneficial to improve the catalytic activity of the double metal cyanide(DMC) catalyst. In this paper poly(propylene carbonate tetrachlorophthalic phthalate)(PPCPA) terpolymers were successfully synthesized from carbon dioxide, propylene oxide and tetrachlorophthalic anhydride catalyzed by ball milling synthesized Zn-Co DMC catalysts. The properties and structures of Zn-Co DMC catalysts and the resulting terpolymers were characterized by Fourier transform infrared spectroscopy(FTIR), scanning electron microscope(SEM), X-ray diffraction(XRD), gel permeation chromatography(GPC) and thermogravimetric analysis(TG). The results show that the turnover number of Zn-Co DMC catalysts is up to 25.67~141.80, and the number-average relative molecular mass of PPCPA is up to 2.21×10³~3.15×10³ with a narrow polydispersity index of 1.04~1.24. Compared with polypropylene carbonate(PPC), PPCPA shows a higher thermal stability, and the thermal decomposition temperature of PPCPA is increased by 129.8℃.
- ball milling,
- Zn-Co double metal cyanide catalysts,
- co-complexing agents,
- tetrachlorophthalic anhydride,
- terpolymerization
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通讯作者: 陈斌, bchen63@163.com

Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling