Citation: SHI Jia, SONG Huangwang, ZHU Qidong, LIN Qiang, ZHU Linhua, LIU Yinghao, ZHONG Wanlin. Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 659-664. doi: 10.11944/j.issn.1000-0518.2018.06.170211 shu

Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China

Corresponding author: LIN Qiang, linqianggroup@163.com ZHU Linhua, zhulinhua1981@163.com
Received Date: 16 June 2017
Revised Date: 7 August 2017
Accepted Date: 1 September 2017

Fund Project: the Natural Science Foundation of Hainan Province 217108the Scientific and Technical Personnel Services Business Projects 2009GJE20014Supported by the Scientific and Technical Personnel Services Business Projects(No.2009GJE20014), the Natural Science Foundation of Hainan Province(No.217108)

Figures(7)

The addition of co-complexing agent is beneficial to improve the catalytic activity of the double metal cyanide(DMC) catalyst. In this paper poly(propylene carbonate tetrachlorophthalic phthalate)(PPCPA) terpolymers were successfully synthesized from carbon dioxide, propylene oxide and tetrachlorophthalic anhydride catalyzed by ball milling synthesized Zn-Co DMC catalysts. The properties and structures of Zn-Co DMC catalysts and the resulting terpolymers were characterized by Fourier transform infrared spectroscopy(FTIR), scanning electron microscope(SEM), X-ray diffraction(XRD), gel permeation chromatography(GPC) and thermogravimetric analysis(TG). The results show that the turnover number of Zn-Co DMC catalysts is up to 25.67~141.80, and the number-average relative molecular mass of PPCPA is up to 2.21×10³~3.15×10³ with a narrow polydispersity index of 1.04~1.24. Compared with polypropylene carbonate(PPC), PPCPA shows a higher thermal stability, and the thermal decomposition temperature of PPCPA is increased by 129.8℃.
- ball milling,
- Zn-Co double metal cyanide catalysts,
- co-complexing agents,
- tetrachlorophthalic anhydride,
- terpolymerization
1. [1]
  Kuran W. Coordination Polymerization of Heterocyclic and Heterounsaturated Monomers[J]. Prog Polym Sci, 1998,23(97):919-992.
2. [2]
  And O I, Kayaki Y, Ikariya T. Aliphatic Poly(urethane-amine)s Synthesized by Copolymerization of Aziridines and Supercritical Carbon Dioxide[J]. Macromolecules, 2005,38(15):6429-6434. doi: 10.1021/ma050549o
3. [3]
  Soga K, Chiang W, Ikeda S. Copolymerization of Carbon Dioxide with Propyleneimine[J]. J Polym Sci A:Polym Chem, 1974,12(1):121-131. doi: 10.1002/pol.1974.170120111
4. [4]
  Wang D. Aliphatic Polycarbonates Synthesized with Carbon Dioxide[J]. Prog Chem, 2002,14(6):462-468.
5. [5]
  Inoue S, Kitamura K, Tsuruta T. Copolymerization of Carbon Dioxide and Epoxide[J]. J Polym Sci Part B, 1969,7:287-292. doi: 10.1002/pol.1969.110070408
6. [6]
  Inoue S, Kobayashi M, Koinuma H. Reactivities of Some Organozinc Initiators for Copolymerization of Carbon Dioxide and Propylene Oxide[J]. Makromol Chem, 1972,155(1):61-73. doi: 10.1002/macp.1972.021550107
7. [7]
  Sugimoto H, Inoue S. Copolymerization of Carbon Dioxide and Epoxide[J]. J Polym Sci Part A, 2004,42(22):5561-5573. doi: 10.1002/(ISSN)1099-0518
8. [8]
  Varghese J K, Dong S P, Jeon J Y. Double Metal Cyanide Catalyst Prepared Using H₃Co(CN)₆, for High Carbonate Fraction and Molecular Weight Control in Carbon Dioxide/Propylene Oxide Copolymerization[J]. J Polym Sci A:Polym Chem, 2013,51(22):4811-4818. doi: 10.1002/pola.v51.22
9. [9]
  Sebastian J, Srinivas D. Effects of Method of Preparation on Catalytic Activity of Co-Zn Double-metal Cyanide Catalysts for Copolymerization of CO₂, and Epoxide[J]. Appl Catal A Gen, 2014,482(5):300-308.
10. [10]
  Kuyper J, Boxhoorn G. Hexacyanometallate Salts Used as Alkene-oxide Polymerization Catalysts and Molecular Sieves[J]. J Catal, 1987,105(1):163-174. doi: 10.1016/0021-9517(87)90016-9
11. [11]
  Zhang W Y, Lu L B, Cheng Y. Clean and Rapid Synthesis of Double Metal Cyanide Complexes Using Mechanochemistry[J]. Green Chem, 2011,13:2701-2703. doi: 10.1039/c1gc15557a
12. [12]
  Zhang W Y, Lin Q, Cheng Y. Double Metal Cyanide Complexes Synthesized by Solvent-free Grinding Method for Copolymerization of CO₂ and Propylene Oxide[J]. J Appl Polym Sci, 2012,123:977-985. doi: 10.1002/app.34544
13. [13]
  Guo Z F, Lin Q, Zhu L H. Nanolamellar Zn-Ni/Co-Ni Catalysts Introduced by Ball Milling for the Copolymerization of CO₂ with Propylene Oxide[J]. Nanosci Nanotechnol Lett, 2014,6:353-356. doi: 10.1166/nnl.2014.1757
14. [14]
  Liu S, Han X, Huang K. Terpolymerization of Carbon Dioxide with Propylene Oxide and ε-Caprolactone:Synthesis, Characterization and Biodegradability[J]. Polym Bull, 2006,56(1):53-62. doi: 10.1007/s00289-005-0466-2
1. [1]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
2. [2]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
3. [3]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
4. [4]
  Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
5. [5]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
6. [6]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
7. [7]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
8. [8]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
9. [9]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
10. [10]
  Kangjuan Cheng , Chunxiao Liu , Youpeng Wang , Qiu Jiang , Tingting Zheng , Xu Li , Chuan Xia . Design of noble metal catalysts and reactors for the electrosynthesis of hydrogen peroxide. Acta Physico-Chimica Sinica, 2025, 41(10): 100112-0. doi: 10.1016/j.actphy.2025.100112
11. [11]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
12. [12]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
13. [13]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
14. [14]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
15. [15]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
16. [16]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
17. [17]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
18. [18]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
19. [19]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
20. [20]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1254)
HTML views(518)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Terpolymers Derived from CO2, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling