Citation: DAI Xiaoyu, QIAO Haiyan, HAN Dongyun, CAO Zubin, ZHANG Xingke. Distillation Separation and Gas Chromatography/Mass Spectrometry Analysis of Fushun Ethylene Bottom Oil[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 714-721. doi: 10.11944/j.issn.1000-0518.2018.06.170169 shu

Distillation Separation and Gas Chromatography/Mass Spectrometry Analysis of Fushun Ethylene Bottom Oil

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113001, China

Corresponding author: QIAO Haiyan, hyqiao2002@126.com
Received Date: 22 May 2017
Revised Date: 10 July 2017
Accepted Date: 25 August 2017

Fund Project: the National Natural Science Foundation of China 21276253Supported by the National Natural Science Foundation of China(No.21276253), the Research Foundation of Liaoning Shihua University(No.2016XJJ-017)the Research Foundation of Liaoning Shihua University 2016XJJ-017

Figures(5)

In order to avoid the aromatics waste and environmental pollution caused by ethylene bottom oil as a crude fuel for combustion, Fushun ethylene bottom oil was subjected to atmospheric distillation to obtain a fraction below 280℃. To achieve separation of ethylene bottom oil, the fraction below 280℃ was cut into 12 fractions(40~150℃, 150~170℃, 170~180℃, 180~190℃. 190~200℃, 200~210℃. 210~220℃, 220~230℃, 230~240℃, 240~250℃, 250~260℃. 260~280℃) by atmospheric distillation unit equipped with packed columns. The obtained 12 fractions were analyzed qualitatively and quantitatively by gas chromatography/mass spectrometry with an HP-5MS capillary column as the stationary phase. We hope it could provide valuable analytical data for the extraction of aromatic hydrocarbons, and the deep processing and utilization of ethylene bottom oil. The results indicate that the distillate below 280℃account for 52.2% of the total amount of ethylene bottom oil in Fushun, and mainly contained aromatic hydrocarbons with 1 to 4 rings. The mass fraction of monocyclic, tricyclic and tetracyclic aromatic hydrocarbons is small. The monocyclic aromatic hydrocarbons are mainly derivatives of benzene and indene that account for 5.8% and 6.172% of ethylene bottom oil in Fushun, respectively. The tricyclic and tetracyclic aromatic hydrocarbons account for 2.998% and mainly are acenaphthene, fluorene, anthracene, phenanthrene, pyrene and so on. The most abundant bicyclic aromatic hydrocarbons in Fushun ethylene bottom oil are naphthalene, followed by β-methylnaphthalene, α-methylnaphthalene and 1, 4-dihydronaphthalene with mass fraction of 41.152%, 16.729%, 12.089% and 9.046%, respectively. This research shows that ethylene bottom oil in Fushun can be used as good feedstock for extracting high value-added aromatic fine chemicals.
- ethylene bottom oil,
- atmospheric distillation,
- gas chromatography/mass spectrometry,
- aromatic hydrocarbons
1. [1]
  WANG Songhan. Ethylene Process and Technology(the Best)[M]. Beijing:China Petrochemical Press, 2012:15-25(in Chinese).
2. [2]
  GE Chuanzhang, LONG Donghui, QIAO Wenming. Structure Analysis and Pyrolysis Behavior of Ethylene Residue[J]. J Pet Sci(Pet Process), 2014,30(6):1052-1058.
3. [3]
  Wu M B, Shi Y Y, Li S B. Synthesis and Characterization of Condensed Poly-Nuclear Aromatic Resin Using Heavy Distillate from Ethylene Tar[J]. New Carbon Mater, 2013,55(6):377-377.
4. [4]
  Kan T, Wang H, Li C. Liquid Fuels From Ethylene Tar by Two-stage Catalytic Hydroprocessing[J]. Energy Sources(Part A Recovery Util Environ Eff), 2015,37(21):2317-2322.
5. [5]
  YANG Jinghua, CAO Zubin, ZHUANG Dan. Aromatic Solvent Naphtha Produced By-Product C9 Factions[J]. Chem Ind Eng Prog, 2007,26(9):1323-1327.
6. [6]
  Wu M, Shi Y, Li S. Synthesis and Characterization of Condensed Polynuclear Aromatic Resin Derived from Ethylene Tar[J]. China Pet Process Petrochem Technol, 2012,14(4):42-47.
7. [7]
  YANG Zhiwu. Preparation and Study of Pitch-Based General Purpose Carbon Fibers from Ethylene Tar[D]. Tianjin: Tianjin University, 2012(in Chinese).
8. [8]
  Andreikov E I, Amosova I S, Dikovinkina Y A. Pyrolysis of Polystyrene in Coal Tar and Ethylene Tar Pitches[J]. Russ J Appl Chem, 2012,85(1):89-97. doi: 10.1134/S1070427212010181
9. [9]
  Cheng X, Zha Q, Zhong J. Needle Coke Formation Derived from Co-Carbonization of Ethylene Tar Pitch and Polystyrene[J]. Fuel, 2009,88(11):2188-2192. doi: 10.1016/j.fuel.2009.05.006
10. [10]
  Yang J, Nakabayashi K, Jin M. Preparation of Isotropic Pitch-based Carbon Fiber Using Hyper Coal Through Co-carbonation with Ethylene Bottom Oil[J]. J Ind Eng Chem, 2016,34:34397-34404.
11. [11]
  Yang J, Nakabayashi K, Jin M. Preparation of Isotropic Spinnable Pitch and Carbon Fiber by the Bromination-Dehydrobromination of Biotar and Ethylene Bottom Oil Mixture[J]. J Mater Sci, 2017,52(2):1165-1171. doi: 10.1007/s10853-016-0412-8
12. [12]
  Han D Y, Cao Z B, Li Y F. Investigation of Naphthalene Extraction from Ethylene Tar[J]. Energy Sources(Part A Recovery Util Environ Eff), 2014,36(9):993-998.
13. [13]
  LI Yanfang, CAO Zubin, LI Dandong. Isolation of β-Methylnaphthalene from Ethylene Tar Through Extraction-Rectification[J]. Chem Ind Eng Prog, 2010,29(11):2049-2052.
14. [14]
  ZHANG Zeng, KAN Yiqun, LIU Feng, et al. Extraction of Naphthalene, 1-Methylnaphthalene and 2-Methylnaphyhalene from Ethylene Tar: CN, 102134500. B[P], 2013-05-15(in Chinese).
15. [15]
  YANG Dongping. Ethylene Tar Integrated Processing Technology: CN, 1970688. B[P], 2010-05-12(in Chinese).
16. [16]
  Islas C A, Suelves I, Carter J F. Pyrolysis-Gas Chromatography/Mass Spectrometry of Fractions Separated from a Low-Temperature Coal Tar:An Attempt to Develop a General Method for Characterising Structures and Compositions of Heavy Hydrocarbon Liquids[J]. Rapid Commun Mass Spectrom, 2002,16(8):774-784. doi: 10.1002/(ISSN)1097-0231
17. [17]
  Morgan T J, George A, Áliarez P. Characterization of Molecular Mass Ranges of Two Coal Tar Distillate Fractions(Creosote and Anthracene Oils) and Aromatic Standards by LD-MS, GC-MS, Probe-MS and Size-Exclusion Chromatography[J]. Energy Fuels, 2008,22(5):3275-3292. doi: 10.1021/ef800333v
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