Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials
- Corresponding author: YANG Jiangfeng, yangjiangfeng@tyut.edu.cn
Citation:
YUAN Ning, DU Bingjie, JIA Xiaoxia, YANG Jiangfeng, LI Jinping. Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials[J]. Chinese Journal of Applied Chemistry,
;2018, 35(5): 500-510.
doi:
10.11944/j.issn.1000-0518.2018.05.170243
Furukawa H, Cordova K E, O'Keeffe M. The Chemistry and Applications of Metal-Organic Frameworks[J]. Science, 2013,341(6149)1230444. doi: 10.1126/science.1230444
Furukawa H, Müller U, Yaghi O M. "Heterogeneity Within Order" in Metal-Organic Frameworks[J]. Angew Chem Int Ed, 2015,54(11):3417-3430. doi: 10.1002/anie.201410252
James S L. Metal-Organic Frameworks[J]. Chem Soc Rev, 2003,32(5):276-288. doi: 10.1039/b200393g
Kitagawa S. Metal-Organic Frameworks(MOFs)[J]. Chem Soc Rev, 2014,43(16):5415-5418. doi: 10.1039/C4CS90059F
Zhou H C, Long J R, Yaghi O M. Introduction to Metal-Organic Frameworks[J]. Chem Rev, 2012,112(2):673-674. doi: 10.1021/cr300014x
He Y, Zhou W, Qian G. Methane Storage in Metal-Organic Frameworks[J]. Chem Soc Rev, 2014,43(16):5657-5678. doi: 10.1039/C4CS00032C
Liu J, Thallapally P K, McGrail B P. Progress in Adsorption-Based CO2 Capture by Metal-Organic Frameworks[J]. Chem Soc Rev, 2012,41(6):2308-2322. doi: 10.1039/C1CS15221A
CHAEMCHUEN S, ZHOU Kui, YAO Chen. Alkali-Metal Tuning of Adsorption Sites in Metal Organic Frameworks MOF-5 for Carbon Dioxide/Methane Separation at Ambient Conditions[J]. Chinese J Appl Chem, 2015,32(5):552-556. doi: 10.11944/j.issn.1000-0518.2015.05.140311
Wu H, Gong Q, Olson D H. Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks[J]. Chem Rev, 2012,112(2):836-868. doi: 10.1021/cr200216x
Li J R, Sculley J, Zhou H C. Metal-Organic Frameworks for Separations[J]. Chem Rev, 2011,112(2):869-932.
Qiu S, Xue M, Zhu G. Metal-Organic Framework Membranes:From Synthesis to Separation Application[J]. Chem Soc Rev, 2014,43(16):6116-6140. doi: 10.1039/C4CS00159A
Van de Voorde B, Bueken B, Denayer J. Adsorptive Separation on Metal-Organic Frameworks in the Liquid Phase[J]. Chem Soc Rev, 2014,43(16):5766-5788. doi: 10.1039/C4CS00006D
Hu Z, Deibert B J, Li J. Luminescent Metal-Organic Frameworks for Chemical Sensing and Explosive Detection[J]. Chem Soc Rev, 2014,43(16):5815-5840. doi: 10.1039/C4CS00010B
McGrail B P, Thallapally P K, Blanchard J. Metal-Organic Heat Carrier Nanofluids[J]. Nano Energy, 2013,2(5):845-855. doi: 10.1016/j.nanoen.2013.02.007
Annapureddy H V, Nune S K, Motkuri R K. A Combined Experimental and Computational Study on the Stability of Nanofluids Containing Metal Organic Frameworks[J]. J Phys Chem B, 2015,119(29):8992-8999. doi: 10.1021/jp5079086
Dhakshinamoorthy A, Garcia H. Metal-Organic Frameworks as Solid Catalysts for the Synthesis of Nitrogen-Containing Heterocycles[J]. Chem Soc Rev, 2014,43(16):5750-5765. doi: 10.1039/C3CS60442J
Liu J, Chen L, Cui H. Applications of Metal Organic Frameworks in Heterogeneous Supramolecular Catalysis[J]. Chem Soc Rev, 2014,43(16):6011-6061. doi: 10.1039/C4CS00094C
Zhang T, Lin W. Metal-Organic Frameworks for Artificial Photosynthesis and Photocatalysis[J]. Chem Soc Rev, 2014,43(16):5982-5993. doi: 10.1039/C4CS00103F
Canivet J, Fateeva A, Guo Y. Water Adsorption in MOFs:Fundamentals and Applications[J]. Chem Soc Rev, 2014,43(16):5594-5617. doi: 10.1039/C4CS00078A
Barea E, Montoro C, Navarro J A. Toxic Gas Removal-Metal-Organic Frameworks for the Capture and Degradation of Toxic Gases and Vapours[J]. Chem Soc Rev, 2014,43(16):5419-5430. doi: 10.1039/C3CS60475F
Jeon J W, Sharma R, Meduri P. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors[J]. ACS Appl Mater Interfaces, 2014,6(10):7214-7222. doi: 10.1021/am500339x
ZHANG Zhuoming, YANG Jiangfeng, WANG Yong. Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks[J]. Chinese J Inorg Chem, 2015,31(4):627-634.
Burrows A D. Mixed-Component Metal-Organic Frameworks(MC-MOFs):Enhancing Functionality Through Solid Solution Formation and Surface Modifications[J]. CrystEngComm, 2011,13(11):3623-3642. doi: 10.1039/c0ce00568a
Han S S, Mendoza-Cortés J L, Goddard Ⅲ W A. Recent Advances on Simulation and Theory of Hydrogen Storage in Metal Organic Frameworks and Covalent Organic Frameworks[J]. Chem Soc Rev, 2009,38(5):1460-1476.
Chun H, Dybtsev D N, Kim H. Synthesis, X-ray Crystal Structures, and Gas Sorption Properties of Pillared Square Grid Nets Based on Paddle-Wheel Motifs:Implications for Hydrogen Storage in Porous Materials[J]. Chem-Eur J, 2005,11(12):3521-3529. doi: 10.1002/(ISSN)1521-3765
Burrows A D, Frost C G, Mahon M F. Post-Synthetic Modification of Tagged Metal-Organic Frameworks[J]. Angew Chem Int Ed, 2008,47(44):8482-8486. doi: 10.1002/anie.v47:44
Wu T, Bu X, Zhang J. New Zeolitic Imidazolate Frameworks:From Unprecedented Assembly of Cubic Clusters to Ordered Cooperative Organization of Complementary Ligands[J]. Chem Mater, 2008,20(24):7377-7382. doi: 10.1021/cm802400f
Zhang W, Shi Y, Li C. Synthesis of Bimetallic MOFs MIL-100(Fe-Mn) as an Efficient Catalyst for Selective Catalytic Reduction of NO(x) with NH3[J]. Catal Lett, 2016,146(10):1956-1964. doi: 10.1007/s10562-016-1840-4
Chen Y Z, Wang C, Wu Z Y. From Bimetallic Metal-Organic Framework to Porous Carbon:High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis[J]. Adv Mater, 2015,27(34):5010-5016. doi: 10.1002/adma.201502315
Zhai Q G, Bu X, Mao C. An Ultra-Tunable Platform for Molecular Engineering of High-Performance Crystalline Porous Materials[J]. Nat Commun, 2016,713645. doi: 10.1038/ncomms13645
Song X, Oh M, Lah M S. Hybrid Bimetallic Metal-Organic Frameworks:Modulation of the Framework Stability and Ultralarge CO2 Uptake Capacity[J]. Inorg Chem, 2013,52(19):10869-10876. doi: 10.1021/ic400844v
Bajpai A, Chandrasekhar P, Govardhan S. Single Crystal-to-Single Crystal Site-Selective Postsynthetic Metal Exchange in a Zn-MOF Based on Semi-Rigid Tricarboxylic Acid and Access to Bimetallic MOFs[J]. Chem-Eur J, 2015,21(7):2759-2765. doi: 10.1002/chem.201406098
Stock N, Biswas S. Synthesis of Metal-Organic Frameworks(MOFs):Routes to Various MOF Topologies, Morphologies, and Composites[J]. Chem Rev, 2011,112(2):933-969.
Braga D, Giaffreda S L, Grepioni F. Mechanochemical Preparation of Molecular and Supramolecular Organometallic Materials and Coordination Networks[J]. Dalton Trans, 2006(10):1249-1263. doi: 10.1039/b516165g
Wang L J, Deng H, Furukawa H. Synthesis and Characterization of Metal-Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals[J]. Inorg Chem, 2014,53(12):5881-5883. doi: 10.1021/ic500434a
Ma S, Sun D, Ambrogio M. Framework-Catenation Isomerism in Metal-Organic Frameworks and Its Impact on Hydrogen Uptake[J]. J Am Chem Soc, 2007,129(7):1858-1859. doi: 10.1021/ja067435s
Ma S, Wang X S, Manis E S. Metal-Organic Framework Based on a Trinickel Secondary Building Unit Exhibiting Gas-Sorption Hysteresis[J]. Inorg Chem, 2007,46(9):3432-3434. doi: 10.1021/ic070338v
Kaur G, Rai R K, Tyagi D. Room-Temperature Synthesis of Bimetallic Co-Zn Based Zeolitic Imidazolate Frameworks in Water for Enhanced CO2 and H2 Uptakes[J]. J Mater Chem A, 2016,4(39):14932-14938. doi: 10.1039/C6TA04342A
LI Zhihua, LIU Hong, SONG Linyong. Synthesis of Dual-Metal Functionalized MOF-74 and Its Adsorption Properties[J]. Chinese J Inorg Chem, 2017,33(2):237-242. doi: 10.11862/CJIC.2017.042
Fu Y, Xu L, Shen H. Tunable Catalytic Properties of Multi-Metal-Organic Frameworks for Aerobic Styrene Oxidation[J]. Chem Eng J, 2016,299:135-141. doi: 10.1016/j.cej.2016.04.102
Zhai Q G, Bu X, Mao C. Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal-Organic Frameworks[J]. J Am Chem Soc, 2016,138(8):2524-2527. doi: 10.1021/jacs.5b13491
Qi Y J, Zhao D, Li X X. Indium-Based Heterometal-Organic Frameworks with Different Nanoscale Cages:Syntheses, Structures, and Gas Adsorption Properties[J]. Cryst Growth Des, 2017,17(3):1159-1165. doi: 10.1021/acs.cgd.6b01538
Lalonde M, Bury W, Karagiaridi O. Transmetalation:Routes to Metal Exchange within Metal-Organic Frameworks[J]. J Mater Chem A, 2013,1(18):5453-5468. doi: 10.1039/c3ta10784a
Wang J H, Zhang Y, Li M. Solvent-Assisted Metal Metathesis:A Highly Efficient and Versatile Route Towards Synthetically Demanding Chromium Metal-Organic Frameworks[J]. Angew Chem Int Ed, 2017,129(23):6578-6582. doi: 10.1002/ange.201701217
Kole G K, Vittal J J. Solid-State Reactivity and Structural Transformations Involving Coordination Polymers[J]. Chem Soc Rev, 2013,42(4):1755-1775. doi: 10.1039/C2CS35234F
YANG Jiangfeng, LI Jinping, JIA Xiaoxia, et al. Method for Preparing Double-Metal MOFs Material through Metal Replacement Aided by Steam: CN, 201610794646. 0[P], 2016-12-14(in Chinese).
Denysenko D, Werner T, Grzywa M. Reversible Gas-Phase Redox Processes Catalyzed by Co-Exchanged MFU-4l(arge)[J]. Chem Commun, 2012,48(9):1236-1238. doi: 10.1039/C2CC16235K
Dinca M, Dailly A, Liu Y. Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites[J]. J Am Chem Soc, 2006,128(51):16876-16883. doi: 10.1002/chem.201204358
Wang X S, Chrzanowski M, Wojtas L. Formation of a Metalloporphyrin-Based Nanoreactor by Postsynthetic Metal-Ion Exchange of a Polyhedral-Cage Containing a Metal-Metalloporphyrin Framework[J]. Chem-Eur J, 2013,19(10):3297-3301. doi: 10.1002/chem.201204358
Bradshaw D, Warren J E, Rosseinsky M J. Reversible Concerted Ligand Substitution at Alternating Metal Sites in an Extended Solid[J]. Science, 2007,315(5814):977-980. doi: 10.1126/science.1135445
Han Y, Chilton N F, Li M. Post-Synthetic Monovalent Central-Metal Exchange, Specific I2 Sensing, and Polymerization of a Catalytic [3 3] Grid of[Cu5ⅡCu4ⅠL6]·(Ⅰ)2·13H2O[J]. Chem-Eur J, 2013,19(20):6321-6328. doi: 10.1002/chem.201204115
Kim M, Cahill J F, Fei H. Postsynthetic Ligand and Cation Exchange in Robust Metal-Organic Frameworks[J]. J Am Chem Soc, 2012,134(43):18082-18088. doi: 10.1021/ja3079219
Wang X J, Li P Z, Liu L. Significant Gas Uptake Enhancement by Post-Exchange of Zinc(Ⅱ) with Copper(Ⅱ) Within a Metal-Organic Framework[J]. Chem Commun, 2012,48(83):10286-10288. doi: 10.1039/c2cc34921c
Zou L, Feng D, Liu T F. A Versatile Synthetic Rroute for the Preparation of Titanium Metal Organic Frameworks[J]. Chem Sci, 2016,7(2):1063-1069. doi: 10.1039/C5SC03620H
Chen Y, Yang C, Wang X. Vapor Phase Solvents Loaded in Zeolite as the Sustainable Medium for the Peparation of Cu-BTC and ZIF-8[J]. Chem Eng J, 2017,313:179-186. doi: 10.1016/j.cej.2016.12.055
Kumar G, Gupta R. Molecularly Designed Architectures-The Metalloligand Way[J]. Chem Soc Rev, 2013,42(24):9403-9453. doi: 10.1039/c3cs60255a
Falkowski J M, Wang C, Liu S. Actuation of Asymmetric Cyclopropanation Catalysts:Reversible Single-Crystal to Single-Crystal Reduction of Metal-Organic Frameworks[J]. Angew Chem Int Ed, 2011,123(37):8833-8837. doi: 10.1002/ange.201104086
Xie Z, Ma L, deKrafft K E. Porous Phosphorescent Coordination Polymers for Oxygen Sensing[J]. J Am Chem Soc, 2009,132(3):922-923.
Kitaura R, Onoyama G, Sakamoto H. Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer[J]. Angew Chem Int Ed, 2004,116(20):2738-2741. doi: 10.1002/(ISSN)1521-3757
Chen B, Zhao X, Putkham A. Surface Interactions and Quantum Kinetic Molecular Sieving for H2 and D2 Adsorption on a Mixed Metal-Organic Framework Mmaterial[J]. J Am Chem Soc, 2008,130(20):6411-6423. doi: 10.1021/ja710144k
Feng D, Gu Z Y, Li J R. Zirconium-Metalloporphyrin PCN-222:Mesoporous Metal Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts[J]. Angew Chem Int Ed, 2012,124(41):10453-10456. doi: 10.1002/ange.201204475
Morris W, Volosskiy B, Demir S. Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal Organic Frameworks[J]. Inorg Chem, 2012,51(12):6443-6445. doi: 10.1021/ic300825s
Chen Y, Hoang T, Ma S. Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework[J]. Inorg Chem, 2012,51(23):12600-12602. doi: 10.1021/ic301923x
Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb2+ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
A:a:Zn-ZIF-8; b.Co25Zn75-ZIF-8; c:Co50Zn50-ZIF-8; d.Co75Zn25-ZIF-8; e.Co90Zn10-ZIF-8; f.Co-ZIF-8