Citation: LENG Shuang, WANG Tao, YANG Min, ZHAO Yanzhi, LU Wei, WANG Ruoming, SUN Guoying. Preparation and Electrochemical Performance of Nitrogen Doped Carbon Materials Based on Polydopamine[J]. Chinese Journal of Applied Chemistry, ;2018, 35(4): 477-483. doi: 10.11944/j.issn.1000-0518.2018.04.170094 shu

Preparation and Electrochemical Performance of Nitrogen Doped Carbon Materials Based on Polydopamine

School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

Corresponding author: SUN Guoying, sunguoying@ccut.edu.cn
Received Date: 31 March 2017
Revised Date: 2 May 2017
Accepted Date: 23 May 2017

Fund Project: the Jilin Science and Technology Development Program 20170101094JCSupported by the National Natural Science Foundation of China(No.21003013), the Jilin Science and Technology Development Program(No.20170101094JC)the National Natural Science Foundation of China 21003013

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Porous carbon materials have been extensively studied in the field of electrode materials for supercapacitor due to their high surface area, excellent electron conductivity and good chemical stability. The composition and pore structure of carbon materials directly affect their electrochemical performance. In order to further improve their capacitance performance, nitrogen doped carbon materials with excellent electrochemical performance were prepared for the first time by high temperature carbonization with polydopamine as precursor and KOH as activator. The surface morphology, structure and composition of the obtained N-doped porous carbon materials were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction spectra(XRD), Fourier transform infrared spectrometer(FT-IR), X-ray photoelectron spectroscopy(XPS) and Raman spectroscopy, respectively. The electrochemical performances were investigated by cyclic voltammetry and galvanostatic charge/discharge in 6 mol/L KOH electrolyte. The results show that the specific capacitance of the material can reach 269 F/g at the current density of 1 A/g due to the synergistic effect of double layer capacitance and pseudocapacitance, and the capacitance still remains 93.5% after 1000 charge-discharge cycles.
- polydopamine,
- nitrogen doped,
- porous carbon material,
- supercapacitor
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