Citation: CHEN Guanghai, BAI Ying, WU Feng, WU Chuan. Two-Dimensional Layered Dicalcium Nitride as Anode Material for Sodium Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2018, 35(3): 366-368. doi: 10.11944/j.issn.1000-0518.2018.03.170425 shu

Two-Dimensional Layered Dicalcium Nitride as Anode Material for Sodium Ion Batteries

CHEN Guanghai ^a ,
BAI Ying ^a ,
WU Feng ^a,b ,
WU Chuan ^a,b,,

a.
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
b.
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China

Corresponding author: WU Chuan, chuanwu@bit.edu.cn
Received Date: 27 November 2017
Revised Date: 13 December 2017
Accepted Date: 27 December 2017

Fund Project: Supported by the National Basic Research Program of China(973 project, No.2015CB251100)the National Basic Research Program of China(973 project) 2015CB251100

Figures(2)

Two-dimensional layered Ca₂N was synthesized via a pyrolysis method with Ca₃N₂ precursor. The component, structure and morphology of Ca₂N were characterized by X-ray diffraction and scanning electron microscope. As a novel anode material of sodium ion batteries, the initial discharge capacity is up to 584 mA·h/g and the reversible capacity is about 180 mA·h/g at a current density of 50 mA/g. Even at a high current density of 2000 mA/g, a capacity of 70 mA·h/g can be retained.
- dicalcium nitride,
- two-dimensional layered structure,
- sodium ion batteries,
- anode material
1. [1]
  Yabuuchi N, Kubota K, Dahbi M. Research Development on Sodium-Ion Batteries[J]. Chem Rev, 2014,114(23):11636-11682. doi: 10.1021/cr500192f
2. [2]
  LI Hui, WU Chuan, WU Feng. Sodium Ion Battery:A Promising Energy-Storage Candidate for Supporting Renewable Electricity[J]. Acta Chim Sin, 2014,72(1):21-29.
3. [3]
  Yim T, Han Y K. Tris(trimethylsilyl) Phosphite as an Efficient Electrolyte Additive to Improve the Surface Stability of Graphite Anodes[J]. ACS Appl Mater Interfaces, 2017,9(38):32851-32858. doi: 10.1021/acsami.7b11309
4. [4]
  Liu Y Y, Merinov B V, Goddard Ⅲ W A. Origin of Low Sodium Capacity in Graphite and Generally Weak Substrate Binding of Na and Mg Among Alkali and Alkaline Earth Metals[J]. Proc Natl Acad Sci USA, 2016,113(14):3735-3739. doi: 10.1073/pnas.1602473113
5. [5]
  Ni Q, Bai Y, Wu F. Polyanion-Type Electrode Materials for Sodium-Ion Batteries[J]. Adv Sci, 2017,41600275. doi: 10.1002/advs.201600275
6. [6]
  Liu J H, Liu X W. Two-Dimensional Nanoarchitectures for Lithium Storage[J]. Adv Mater, 2012,24(30):4097-4111. doi: 10.1002/adma.201104993
7. [7]
  Hu J P, Xu B, Yang S A. 2D Electrides as Promising Anode Materials for Na-Ion Batteries from First-Principles Study[J]. ACS Appl Mater Interfaces, 2015,7(43):24016-24022. doi: 10.1021/acsami.5b06847
8. [8]
  Gregory D H, Bowman A, Baker C F. Dicalcium Nitride, Ca₂N-A 2D "Excess Electron" Compound; Synthetic Routes and Crystal Chemistry[J]. J Mater Chem, 2000,10(7):1635-1641. doi: 10.1039/b001911i
9. [9]
  Lee K, Kim S W, Toda Y. Dicalcium Nitride as a Two-Dimensional Electride with an Anionic Electron Layer[J]. Nature, 2013,494(7437):336-340. doi: 10.1038/nature11812
10. [10]
  Chen G H, Bai Y, Li H. Multilayered Electride Ca₂N Electrode via Compression Molding Fabrication for Sodium Ion Batteries[J]. ACS Appl Mater Interfaces, 2017,9(8):6666-6669. doi: 10.1021/acsami.6b16186
11. [11]
  Naguib M, Mashtalir O, Carle J. Two-Dimensional Transition Metal Carbides[J]. ACS Nano, 2012,6(2):1322-1331. doi: 10.1021/nn204153h
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沈阳化工大学材料科学与工程学院沈阳 110142