Citation: ZHAO Liping, WANG Zhen, DONG Xiandui. Effect of Ionic Liquid on the Performance of Perovskite Solar Cells[J]. Chinese Journal of Applied Chemistry, ;2018, 35(2): 216-223. doi: 10.11944/j.issn.1000-0518.2018.02.170106 shu

Effect of Ionic Liquid on the Performance of Perovskite Solar Cells

ZHAO Liping ^a,b ,
WANG Zhen ^a,, ,
DONG Xiandui ^a,,

a.
Polymer Composites Engingeering Laboratory, Changchun Institute of Applied Chemistry, Chinese Acdemy of Sciences, Changchun 130022, China
b.
University of Chinese Acdemy of Sciences, Beijing 100049, China

Corresponding author: WANG Zhen, wangzhen@ciac.ac.cn DONG Xiandui, dxd@ciac.ac.cn
Received Date: 12 April 2017
Revised Date: 15 May 2017
Accepted Date: 3 July 2017

Fund Project: the Science and Technology Support Project of Jiangsu Province BE2014147Supported by the Science and Technology Support Project of Jiangsu Province(No.BE2014147)

Figures(7)

Controling the morphology of the perovskite film is an effective way to improve the photoelectric conversion efficiency of the cells. In this work, 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide(EMITFSI), 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl] imide(HMITFSI) and 1-ethyl-3-methy-limidazolium bis(fluorosulfonyl) imide(EMIFSI) were prepared. Perovskite active layers were dealed with ionic liquid dispersed into the chlorobenzene solution, the morphology of the perovskite layer and the performance of perovskite solar cells were investigated. The results indicate that the fill factor of perovskite solar cells dealed with HMITFSI is enhanced from 0.71 to 0.74, and the photoelectric conversion efficiency is increased, and that the morphology of perovskite is also improved. However, the performance of perovskite solar cells dealed with EMITFSI and EMIFSI are declined. It is HMI cation that improves the morphology of perovskite.
- ionic liquid,
- perovskite,
- soaking treatment,
- morphology
1. [1]
  Kojima A, Teshima K, Shirai Y. Organometal Halide Perovskites as Visible-light Sensitizers for Photovoltaic Cells[J]. J Am Chem Soc, 2009,131(17):6050-6051. doi: 10.1021/ja809598r
2. [2]
  Im J H, Lee C R, Lee J W. 6.5% Efficient Perovskite Quantum-dot-sensitized Solar Cell[J]. Nanoscale, 2011,3(10):4088-4093. doi: 10.1039/c1nr10867k
3. [3]
  Kim H S, Lee C R, Im J H. Lead Iodide Perovskite Sensitized All-solid-state Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%[J]. Sci Rep, 2012,2591. doi: 10.1038/srep00591
4. [4]
  Saliba M, Matsui T, Domanski K. Incorporation of Rubidium Cations into Perovskite Solar Cells Improves Photovoltaic Performance[J]. Scince, 2016,354(6309):206-209. doi: 10.1126/science.aah5557
5. [5]
  SHAO Zhipeng, PAN Xu, ZHANG Xuhui. Influence of Structure and Morphology of Perovskite Films on the Performance of Perovskite Solar Cells[J]. Acta Chim Sin, 2015,73(3):267-271.
6. [6]
  ZHU Lifeng, SHI Jiangjian, LI Dongmei. Effect of Mesoporous TiO₂ Layer Thickness on the Cell Performance of Perovskite Solar Cells[J]. Acta Chim Sin, 2015,73(3):261-266.
7. [7]
  Kim J K, Matic A, Ahn J H. An Imidazolium Based Ionic Liquid Electrolyte for Lithium Batteries[J]. J Power Sources, 2010,195(22):7639-7643. doi: 10.1016/j.jpowsour.2010.06.005
8. [8]
  Shamsipur M, Beigi A A M, Termouri M. Physical and Electrochemical Properties of Ionic Liquids 1-Ethyl-3-methylimidazolium Etrafluoroborate, 1-Butyl-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methyl-pyrrolidinium Bis(trifluoromethylsulfonyl)mide[J]. J Mol Liq, 2010,157(1):43-50. doi: 10.1016/j.molliq.2010.08.005
9. [9]
  Balducci A, Bardi U, Caporali S. Ionic Liquids for Hybrid Supercapacitors[J]. Electrochem Commun, 2004,6(6):566-570. doi: 10.1016/j.elecom.2004.04.005
10. [10]
  Balducci A, Dugas R, Taberna P L. High Temperature Carbon-carbon Supercapacitor Using Ionic Liquid as Electrolyte[J]. J Power Sources, 2007,165(2):922-927. doi: 10.1016/j.jpowsour.2006.12.048
11. [11]
  Padiha J C, Basso J, Trindade L. Ionic Liquids in Proton Exchange Membrane Fuel Cells:Efficient Systems for Energy Generation[J]. J Power Sources, 2010,195(19):6483-6485. doi: 10.1016/j.jpowsour.2010.04.035
12. [12]
  Schmid C, Gluck T, Schmidt-Naake G. Modification of Nafion Membranes by Impregnation with Ionic Liquids[J]. Chem Eng Technol, 2008,31(1):13-22. doi: 10.1002/(ISSN)1521-4125
13. [13]
  ZHANG Yingfeng, LI Changjiang, BAO Fushan. Classification, Synthesis and Application of Ionic Liquids[J]. Chinese J Chem Educ, 2005,26(2):7-12.
14. [14]
  Michot C, Armand M, Gauthier M, et al. Materials Useful as Electrolytic Solutes: US Patent 6365301[P], 2002.
15. [15]
  Eperon G E, Burlakov V M, Docampo P. Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells[J]. Adv Funct Mater, 2014,24(1):151-157. doi: 10.1002/adfm.v24.1
16. [16]
  Che M, Zhu Y L, Yao D S. Enhancing Current Density of Perovskite Solar Cells Using TiO₂-ZrO₂ Composite Scaffold Layer[J]. Mater Sci Semicond Process, 2016,56:29-36. doi: 10.1016/j.mssp.2016.07.003
17. [17]
  Liu M, Johnston M B, Snaith H J. Efficient Planar Heterojunction Perovskite Solar Cells by Vapour Deposition[J]. Nature, 2013,501(7467):395-398. doi: 10.1038/nature12509
18. [18]
  Im J H, Jang I H, Pellet N. Growth of CH₃NH₃PbI₃ Cuboids with Controlled Size for High-efficiency Perovskite Solar Cells[J]. Nat Nanotechnol, 2014,9(11):927-932. doi: 10.1038/nnano.2014.181
19. [19]
  You J, Hong Z, Yang Y. Low-temperature Solution-processed Perovskite Solar Cells with High Efficiency and Flexibility[J]. ACS Nano, 2014,8(2):1674-1680. doi: 10.1021/nn406020d
1. [1]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
2. [2]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
5. [5]
  Haiying Wang , Andrew C.-H. Sue . How to Visually Identify Homochiral Crystals. University Chemistry, 2024, 39(3): 78-85. doi: 10.3866/PKU.DXHX202309004
6. [6]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
7. [7]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
8. [8]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . 高效靶向示踪钙钛矿纳米系统光电增效抗肿瘤. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-. doi: 10.1016/j.actphy.2024.100042
9. [9]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
10. [10]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
11. [11]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
12. [12]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
13. [13]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
14. [14]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
15. [15]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
16. [16]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
17. [17]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
18. [18]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
19. [19]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
20. [20]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(648)
HTML views(119)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142