Citation: GU Zhimeng, WANG Ying, ZHAO Min, HAO Qiuhua, SHANG Di, BAI Fengying, XING Yongheng. Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes[J]. Chinese Journal of Applied Chemistry, ;2018, 35(2): 206-215. doi: 10.11944/j.issn.1000-0518.2018.02.170084 shu

Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes

College of Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: BAI Fengying, baifengying2003@163.com

^‡

Received Date: 27 March 2017
Revised Date: 11 May 2017
Accepted Date: 22 June 2017

Fund Project: the Liaoning Province Students Innovation and Entrepreneurship Projects 201610165047Supported by the National Natural Science Foundation of China(No.21571091), the Liaoning Province Students Innovation and Entrepreneurship Projects(No.201610165047)the National Natural Science Foundation of China 21571091

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As the photocatalytic reaction has the advantages of non-pollution, safe and efficient, so it has become a research hotspot of environmental protecting field. Therefore, this work choose 2, 4-two (3, 5-two methyl pyrazole)-6-two ethyl amine-1, 3, 5-three triazine(L₁) and 2, 6-di[3-(5-methylpyrazolyl)] pyridine(L₂) as the ligands, RuCl₃ as the metal source to synthesize three kinds of complexes, [Ru(L₁)Cl₃](1), [Ru(L₂)₂]·Cl₃(2), and[Ru(L₂)₂]·(H₂BTC)·(HBTC)·H₂O(3). At the same time, the complexes were characterized by infrared(IR) spectrometry, ultraviolet-visible(UV-Vis), themogravimetry(TG) and X-ray diffraction, and the photocatalytic degradation of RhB was explored. The results show that the complexes 1~3 have a certain degree of photodegradation effect, the degradation efficiency is 46.8%, 44.7% and 40.4%, respectively. Under the same conditions, the degradation effects of the complexes are better than those corresponding only with metal salts, ligands and H₂O₂, respectively.
- triazine-pyrazole derivatives,
- ruthenium complexes,
- crystal structure,
- photocatalytic performance
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